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Updated: Feb 11, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

异金属有机框架的新家族中的可编程拓

Patrick F Muldoon¹, Chong Liu¹, Carson C Miller¹

¹Department of Chemistry , University of Pittsburgh , Pittsburgh , Pennsylvania 15260 , United States.

Journal of the American Chemical Society

|May 4, 2018

概括

研究人员开发了一种使用多个金属离子合成复杂金属有机框架 (MOF) 的新策略. 这种方法可以精确控制无机建筑单元的组装,创造具有独特特性的新型MOF结构.

科学领域:

材料科学
无机化学
晶体学

背景情况:

金属有机框架 (MOF) 通过各种构建块提供可调节的特性.
用多个金属离子合成MOF在控制组装和拓方面存在重大挑战.
现有的网状化学方法对于涉及两个以上构件的复杂MOF合成是有限的.

研究的目的:

制定一项系统和差异化控制多种金属在MOF中的协调策略.
为了使复杂的异金属MOF与受控结构的合成.
通过精确组装无机二级建筑单元 (SBU) 探索新的MOF拓.

主要方法:

使用双功能异酸连接剂和衍生品来区分金属协调.
使用单溶热反应来控制多个无机SBU的组装.
设计的MOF含有M6 ((μ3-O) n ((μ3-OH) 8-nM ((CO2) 12) (M=Zr4+,Hf4+,Dy3+) 的SBU和金属-基复合物.

主要成果:

成功合成了多种不同的异金属MOF与多达三种不同的无机SBU.
通过利用链接器的协调特性,对MOF组件和拓进行了证明.
实现了8个新的MOF结构,包括使用fcu,ftw和新型三极管 pfm晶体网.

结论:

开发的策略允许精确控制具有多个金属离子和SBU的复杂MOF的构造.
这种方法扩大了设计具有定制性质和新兴功能的MOF的可能性.
像pfmnet这样的新型MOF拓的合成,为材料科学和网状化学开辟了新的途径.

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