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相关概念视频

Alkali Metals03:06

Alkali Metals

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Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
24.9K
Histone Modification02:32

Histone Modification

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The histone proteins have a flexible N-terminal tail extending out from the nucleosome. These histone tails are often subjected to post-translational modifications such as acetylation, methylation, phosphorylation, and ubiquitination. Particular combinations of these modifications form “histone codes” that influence the chromatin folding and tissue-specific gene expression.
Acetylation
The enzyme histone acetyltransferase adds acetyl group to the histones. Another enzyme, histone...
16.2K
Metal-Ligand Bonds02:51

Metal-Ligand Bonds

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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
24.4K
Pre-mRNA Processing: Modification of pre-mRNA Ends01:35

Pre-mRNA Processing: Modification of pre-mRNA Ends

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In eukaryotic cells, transcripts made by RNA polymerase are modified and processed before exiting the nucleus. Unprocessed RNA is called precursor mRNA or pre-mRNA to distinguish it from mature mRNA.
Once about 20-40 ribonucleotides have been joined together by RNA polymerase, a group of enzymes adds a cap to the 5' end of the growing transcript. In this process, a 5' phosphate is replaced by modified guanosine that has a methyl group attached (7-methyl guanosine). This 5' cap helps...
15.5K
Spreading of Chromatin Modifications02:25

Spreading of Chromatin Modifications

9.5K
The histone proteins in the nucleosomes are post-translationally modified (PTM) to increase or decrease access to DNA. The commonly observed PTMs are methylation, acetylation, phosphorylation, and ubiquitination of lysine amino acids in the histone H3 tail region. These histone modifications have specific meaning for the cell. Hence, they are called "histone code". The protein complex involved in histone modification is termed as "reader-writer" complex.
Writers
The writer...
9.5K
Properties of Transition Metals02:58

Properties of Transition Metals

30.0K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
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相关实验视频

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Clean Sampling and Analysis of River and Estuarine Waters for Trace Metal Studies
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Clean Sampling and Analysis of River and Estuarine Waters for Trace Metal Studies

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对高度稳定的金属有机子的组装后修改的过程跟踪研究

Guoliang Liu1, Yi Di Yuan1, Jian Wang1

  • 1Department of Chemical and Biomolecular Engineering , National University of Singapore , 4 Engineering Drive 4 , 117585 Singapore.

Journal of the American Chemical Society
|May 4, 2018
PubMed
概括

金属有机 (MOCs) 在各种pH值的水溶液中表现出显著的稳定性. 这项研究突显了它们作为各种应用的多功能平台的潜力,克服了以前的限制.

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Synthesis and Exfoliation of Discotic Zirconium Phosphates to Obtain Colloidal Liquid Crystals
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相关实验视频

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科学领域:

  • 材料科学
  • 超分子化学
  • 纳米技术

背景情况:

  • 金属有机 (MOCs) 是有前途的分子组件,在各种领域都有潜在的应用.
  • 由于MOC的稳定性不足,特别是在水环境中,使其无法广泛应用.
  • 基于的MOC (Zr-MOC) 是一种具有提高稳定性的材料.

研究的目的:

  • 详细研究几个Zr-MOC在水溶液中的稳定性.
  • 探索Zr-MOC作为组装后修改平台的潜力.
  • 展示Zr-MOC在各种应用中的多功能性.

主要方法:

  • 多个Zr-MOC的合成和表征.
  • 在酸性,中性和弱性水条件下对Zr-MOC稳定性的系统评估.
  • 在特定的Zr-MOC (ZrT-1-NH2) 上进行组装后修改的过程追踪研究.

主要成果:

  • 一些Zr-MOC在广泛的pH范围 (酸性,中性和弱基性) 的水溶液中表现出极好的稳定性.
  • ZrT-1-NH2的组装后修改成功实现并追踪,证明了该材料的多功能性.
  • 这些发现表明Zr-MOC可以克服传统MOC的稳定性限制.

结论:

  • Zr-MOC是一种强大的材料,具有实用应用的巨大潜力.
  • 证明Zr-MOC的稳定性和多功能性使它们成为有价值的分子平台.
  • 这项研究为基于Zr-MOC的先进功能材料的开发铺平了道路.