通过构成块的J和H聚合来控制双组件水凝的超分子性
Guofeng Liu1, Jianhui Sheng1,2, Hongwei Wu1
1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences , Nanyang Technological University , 21 Nanyang Link , 637371 , Singapore.
Journal of the American Chemical Society
|May 8, 2018
概括
研究人员使用基于氨酸的分子和状添加剂创建了可调节的螺旋纳米结构. 这一突破为超分子性提供了洞察力,并使性纳米结构的精确制造成为可能.
科学领域:
- 超分子化学
- 材料科学
- 奇拉性研究
背景情况:
- 操纵纳米结构螺旋是具有挑战性的,但对于理解螺旋系统至关重要.
- 了解自我组装中的超分子性是关键的研究领域.
- 以功能为导向的堆叠模式,如J和H聚合,影响纳米结构的性.
研究的目的:
- 在自我组装中研究超分子性质的起源和控制.
- 开发一种具有可调节性质的螺旋纳米纤维的方法.
- 探索构建块聚合在螺旋反转中的作用.
主要方法:
- 使用基于氨酸的反体和阿基拉 bis (pyridinyl) 衍生物制备双成分水凝.
- 构成螺旋式纳米纤维的构建块的固体测量组合.
- 使用循环二重化,扫描电子显微镜,富里埃变换红外光谱学和单射线晶体学进行表征.
主要成果:
- 有反向手的螺旋纳米纤维,可控制的度和直径已成功合成.
- 通过 bis ((pyridinyl) 衍生物的 J 和 H 聚合模式的过渡来实现螺旋逆转.
- 通过使用体构成块或通过与相同配置的体单体交换体添加剂来获得相反的手性.
结论:
- 这项研究阐明了分子自组的起源和螺旋性逆转机制.
- 提供了精确制造性纳米结构的途径.
- 突出了智能显示设备,光电子和生物系统的潜在应用.
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