通过热切换金属连接体电子转移的铁半形单链磁体
Jordan A DeGayner1, Kunyu Wang1, T David Harris1
1Department of Chemistry , Northwestern University , Evanston , Illinois 60208-3313 , United States.
Journal of the American Chemical Society
|May 12, 2018
概括
研究人员通过金属体电子转移合成了一种新型半体桥接单链磁体. 这种材料表现出温度诱导的旋转转变,并表现出缓慢的磁性放松,为分子磁性提供了一个新的平台.
科学领域:
- 分子磁性
- 协调化学
- 材料科学
背景情况:
- 单链磁铁 (SCM) 是具有一维链的磁性排序的分子材料.
- 金属连体电子转移是协调化合物中调节磁性特性的关键机制.
研究的目的:
- 合成和描述一个新型的半形桥式单链磁铁.
- 调查温度依赖的磁性行为和电子转移机制.
主要方法:
- 从FeCl3和2,5-二-3,6-二-1,4-基 (LH2) 中合成 (NMe4) 2[LFeCl2].
- 可变温度X射线衍射,莫斯巴尔光谱,拉曼光谱和磁感应度测量 (dc和ac).
主要成果:
- 观察到一种热诱导的金属-联体电子转移,导致从 (L2-) FeII到 (L3-) FeIII单位在213K.
- 证实了强大的金属根合 (J = -81 cm-1) 和缓慢的磁放松 (Δτ = 55(1) cm-1).
- 该化合物代表了半形桥接单链磁体的第一个例子.
结论:
- 一个半形桥梁SCM的成功合成开辟了分子磁性的新途径.
- 观察到的旋转转移和磁放松特性凸显了这种材料在旋转应用中的潜力.
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