一个单碳酸功能化的"德克萨斯大小"分子盒的超分子特性
Ren-Tsung Wu1, Xiaodong Chi1, Takehiro Hirao1
1Department of Chemistry , The University of Texas at Austin , Austin , Texas 78712-1224 , United States.
Journal of the American Chemical Society
|May 15, 2018
概括
一个新的分子盒,TxSB-CO2H,在固态中形成一个二元体,但在溶液中自组装成一个对刺激有反应的小分子体. 这种可逆组合可以创建基于分子盒宏循环的可适应材料.
科学领域:
- 超分子化学
- 材料科学
- 有机化学
背景情况:
- 分子盒是宏循环化合物,在材料科学中具有潜在的应用.
- 了解功能化分子盒的聚合行为对于设计响应材料至关重要.
- 碳酸功能组可以影响自组和溶液的行为.
研究的目的:
- 合成和描述一种新的碳酸功能化分子盒,TxSB-CO2H.
- 研究TxSB-CO2H及其结合基在溶液和固态中的聚合行为.
- 探索自我组装结构的刺激反应性质.
主要方法:
- 通过催化宏循环合成TxSB-CO2H.
- 使用单晶X射线衍射进行结构特征.
- 使用1H NMR光谱,动态光散射 (DLS) 和扫描电子显微镜 (SEM) 的溶液行为分析.
主要成果:
- 在固态状态下,TxSB-CO2H形成了一个类似剪贴的二元体.
- 结合基,TxSB-CO2-,在溶液中自组成一个稳定的寡合体 ([TxSB-CO2-]n,n≈5-6).
- 自组合的寡合体对度,温度,质子状态和离子存在的变化表现出刺激反应的行为.
结论:
- 功能化分子盒可以设计成对刺激有反应的超分子材料.
- 在TxSB-CO2的自我组合中,可以发现可逆的非共价相互作用.
- 固态聚合不一定决定溶液阶段的行为,强调了这些系统的动态性质.
相关概念视频
Molecular Models
Physical models representing molecular architectures of chemical compounds play essential roles in understanding chemistry. The use of molecular models makes it easier to visualize the structures and shapes of atoms and molecules.
Acid Strength and Molecular Structure
Binary Acids and Bases
In the absence of any leveling effect, the acid strength of binary compounds of hydrogen with nonmetals (A) increases as the H-A bond strength decreases down a group in the periodic table. For group 17, the order of increasing acidity is HF < HCl < HBr < HI. Likewise, for group 16, the order of increasing acid strength is H2O < H2S < H2Se < H2Te. Across a row in the periodic table, the acid strength of binary hydrogen compounds increases with increasing...
In the absence of any leveling effect, the acid strength of binary compounds of hydrogen with nonmetals (A) increases as the H-A bond strength decreases down a group in the periodic table. For group 17, the order of increasing acidity is HF < HCl < HBr < HI. Likewise, for group 16, the order of increasing acid strength is H2O < H2S < H2Se < H2Te. Across a row in the periodic table, the acid strength of binary hydrogen compounds increases with increasing...
Molecular Structure and Acidity
An acid can be deprotonated to form a conjugate base or an anion. If the produced anion is more stable, then the acid is stronger. On the contrary, if the anion is unstable, then the acid is weaker. Hence, to determine the acidity of the compound, the stability of its conjugate base is studied using various factors.
The size effect explains the change in atomic size on acidity. When comparing the acids formed from elements that belong to the same column in the periodic table, their atomic sizes...
The size effect explains the change in atomic size on acidity. When comparing the acids formed from elements that belong to the same column in the periodic table, their atomic sizes...
Carboxylic Acid Derivatives: Overview
Carboxylic acid derivatives are formed by replacing the hydroxyl group of carboxylic acids with a different functional group. The most common carboxylic acid derivatives are:
Physical Properties of Carboxylic Acid Derivatives
Intermolecular forces dictate several physical properties such as boiling points, melting points, solubilities, and so forth. They are classified into four types: ionic forces, hydrogen bonds, dipole–dipole forces, and dispersion forces. Ionic forces are the strongest, while dispersion forces are the weakest.
Among the carboxylic acid derivatives, the boiling points of acid chlorides and esters are very similar and are the lowest in the series. Acid anhydrides have slightly higher boiling...
Among the carboxylic acid derivatives, the boiling points of acid chlorides and esters are very similar and are the lowest in the series. Acid anhydrides have slightly higher boiling...
Physical Properties of Carboxylic Acids
Carboxylic acids with lower molecular weight exhibit a sharp and unpleasant odor. They also have higher boiling and melting points than analogous compounds, such as aldehydes, ketones, and alcohols.


