水分数对离子界面传输的影响
Jinbo Peng1,2, Duanyun Cao1, Zhili He3
1International Center for Quantum Materials, School of Physics, Peking University, Beijing, China.
Nature
|May 16, 2018
概括
与三个水分子相结合的离子 (Na+) 在表面扩散速度明显快. 这种增强的移动性是由于独特的转移稳定状态使集体水分子旋转成为可能,这对于理解离子运输至关重要.
科学领域:
- 表面科学
- 物理化学
- 纳米技术
背景情况:
- 在各种自然和应用领域中,离子水合和传输至关重要.
- 在有限的纳米尺度几何体中,界面效应变得更加明显,改变了离子运输机制.
研究的目的:
- 将水合离子的原子结构与它们在表面上的运输特性联系起来.
- 探究控制离子,水和表面动态的分子级相互作用.
主要方法:
- 通过附着水分子在NaCl (001) 表面上构建单个离子 (Na+) 水合物.
- 使用了扫描道显微镜和非接触式原子力显微镜的组合.
- 进行了初始计算和古典分子动力学模拟.
主要成果:
- 与其他水合物相比,离子 (Na+) 水合物的扩散率高出数量级.
- 在初始计算中,发现了一个超稳定状态,使三种水分子在低能量屏障下共同旋转.
- 分子动力学模拟证实这种现象即使在室温下也是相关的.
结论:
- 异常高的离子扩散率与特定的水合数和离子水合物和表面格子之间的对称性匹配.
- 这些发现为界面上的离子运输机制提供了分子层面的洞察力,特别是在封闭系统中.
更多相关视频
09:43Interfacial Molecular-level Structures of Polymers and Biomacromolecules Revealed via Sum Frequency Generation Vibrational Spectroscopy
Published on: August 13, 2019
9.9K
10:03Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
Published on: November 11, 2013
26.1K
相关概念视频
Pore Transport and Ion-Pair Transport
1.3K
Pore transport and ion-pair formation are critical mechanisms for the absorption and distribution of drugs in the body.
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
1.3K
Aqueous Solutions and Heats of Hydration
18.0K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
18.0K
Ions as Acids and Bases
26.6K
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
26.6K
Secondary Active Transport
138.1K
One example of how cells use the energy contained in electrochemical gradients is demonstrated by glucose transport into cells. The ion vital to this process is sodium (Na+), which is typically present in higher concentrations extracellularly than in the cytosol. Such a concentration difference is due, in part, to the action of an enzyme “pump” embedded in the cellular membrane that actively expels Na+ from a cell. Importantly, as this pump contributes to the high concentration of...
138.1K
Primary Active Transport
200.7K
In contrast to passive transport, active transport involves a substance being moved through membranes in a direction against its concentration or electrochemical gradient. There are two types of active transport: primary active transport and secondary active transport. Primary active transport utilizes chemical energy from ATP to drive protein pumps that are embedded in the cell membrane. With energy from ATP, the pumps transport ions against their electrochemical gradients—a direction...
200.7K
Formation of Complex Ions
26.2K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
26.2K
