从溶液到表面分类分子构成块
Hodaya Keisar1, Graham de Ruiter1, Aldrik H Velders2
1Department of Organic Chemistry , The Weizmann Institute of Science , 7610001 Rehovot , Israel.
Journal of the American Chemical Society
|May 17, 2018
概括
复合物主要与有机单层结合,形成分子梯度. 由于复杂包装的微妙差异,这种选择性结合会导致金属复杂物在表面的分布不均.
科学领域:
- 表面化学
- 材料科学
- 纳米技术
背景情况:
- 有机单层作为精确分子组装的平台.
- 控制金属复合物在表面上的分布对于高级应用至关重要.
研究的目的:
- 在有机单层上使用和复合物的分子梯度的形成.
- 了解影响这些金属复合物的选择性结合和分布的因素.
主要方法:
- 在或金属氧化物表面上制造1,3,5-tris(4-pyridylethenyl) (TPEB) 有机单层.
- 将单层暴露在含有等等量和复合物的溶液中.
- 用光谱和计算分析来描述分子分布和包装.
主要成果:
- 观察到一个和复合物的分子梯度,与表面平面直角,延伸超过30nm.
- 在使用不同的有机单层或金属复合物时形成了均和等分的分布.
- 复杂的几何和联体电子特性中的微妙差异导致了修改的表面上不同的包装行为.
结论:
- 有机单层的结构和金属复合物的微妙差异显著地影响了它们的包装和分布.
- 复合物的优先结合会产生分子梯度,从而实现受控的表面组成.
- 这一发现为设计具有量身定制化学特性的功能化表面提供了途径.
相关概念视频
Local Anesthetics: Clinical Application as Surface, Infiltration, and Conduction Block Anesthesia
2.1K
Depending on the target organ, local anesthetics (LAs) can be administered via various routes. In surface anesthesia, LAs are applied directly to the surface of the skin or mucous membranes. It is widely used for topical skin numbing before venipuncture or minor surgical procedures. Commonly used surface local anesthetics are lidocaine or benzocaine sprays or creams. Surface anesthesia occurs within 5 minutes and lasts for about 60 minutes. One of the main disadvantages of topical anesthesia is...
2.1K
Electrolyte and Nonelectrolyte Solutions
72.1K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
72.1K
Movement Joints in Buildings
360
Movement joints in buildings are essential design elements that accommodate inevitable motions caused by various factors such as temperature changes, moisture content variations, and structural deflections. These motions, if not considered in design and construction, can lead to unsightly or dangerous damage. Movement joints are incorporated in different forms to manage these stresses and allow materials to move without causing distress.
The simplest type of movement joints, working joints, are...
The simplest type of movement joints, working joints, are...
360
Types of Building Stone
458
Building stones, essential materials for construction, are extracted from natural rock deposits and processed into specific forms and dimensions suitable for various building applications. These stones are broadly classified into three types based on their geological formation: igneous, sedimentary, and metamorphic.
Igneous rocks are formed from the solidification of magma or lava. An example is granite, known for its durability and resistance to weathering, making it ideal for parts of...
Igneous rocks are formed from the solidification of magma or lava. An example is granite, known for its durability and resistance to weathering, making it ideal for parts of...
458
Chemical Reactions in Aqueous Solutions
72.7K
Chemical substances interact in many different ways. Certain chemical reactions exhibit common patterns of reactivity. Due to the vast number of chemical reactions, it becomes necessary to classify them based on the observed patterns of interaction.
72.7K
Ideal Solutions
22.7K
According to Raoult’s law, the partial vapor pressure of a solvent in a solution is equal or identical to the vapor pressure of the pure solvent multiplied by its mole fraction in the solution. However, Raoult's Law is only valid for ideal solutions. For a solution to be ideal, the solvent-solute interaction must be just as strong as a solvent-solvent or solute-solute interaction. This suggests that both the solute and the solvent would use the same amount of energy to escape to the...
22.7K


