通过大气和移动离子调节分子电子设备的内部电场
Prakash Chandra Mondal1, Ushula M Tefashe1, Richard L McCreery1
1Department of Chemistry , University of Alberta , Edmonton , Alberta T6G 2G2 , Canada.
Journal of the American Chemical Society
|May 18, 2018
概括
移动离子和酸显著改变分子结电导和电子行为. 这种离子运动和分子重定向提供了对设备属性的动态控制.
科学领域:
- 分子电子
- 固态化学
- 材料科学
背景情况:
- 分子电子连接由内部电位配置和电场控制.
- 电化学过程依赖于电解离子对电场的改变,形成离子双层.
研究的目的:
- 研究移动离子对固态分子结合的影响.
- 在引入离子时分析芳香分子和导电碳表面的导电变化.
主要方法:
- 制造碳表面之间的分子连接与芳香分子.
- 将乙和离子引入连接点
- 导电,阻抗和电流电压特征的测量.
- 暂时的实验观察时间尺度上的变化.
主要成果:
- 单独使用乙导致电导率的变化很小;与离子一起使用导致电导率的大幅下降.
- 导电变化发生在微秒到毫秒的时间尺度上,影响了设备阻抗和温度依赖性.
- 一个与酸的分子结合显示了可逆转换从对称到纠正行为.
结论:
- 酸和离子运动屏电极的场诱导重定位,修改内部电位配置.
- 这些离子效应提供了一种动态控制分子结的电子行为的方法.
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