原子力显微镜纳米机械映射可视化化学交换反应导致网络之间的界面扩展
Changfei He1, Shaowei Shi1, Xuefei Wu1
1Beijing Advanced Innovation Center for Soft Matter Science and Engineering & State Key Laboratory of Organic-Inorganic Composites , Beijing University of Chemical Technology , Beijing 100029 , China.
Journal of the American Chemical Society
|May 19, 2018
概括
在环氧网络中的界面扩展会产生具有混合性质的新材料. 纳米机械绘制揭示了交换反应,并允许测量反应动力学和激活能量.
科学领域:
- 聚合物科学
- 材料科学
- 纳米技术
背景情况:
- 对于复合材料来说,了解接口特性至关重要.
- 环氧网被广泛用于粘合剂和涂料.
- 聚合物网络中的差分模块可以导致独特的界面行为.
研究的目的:
- 用不同的模块绘制两个环氧网络之间的界面扩展.
- 调查一个带有分级属性的界面区域的形成.
- 通过交换反应确定细分混合的动力学和激活能量.
主要方法:
- 纳米机械绘制分析接口扩展.
- 测量模块随时间和温度的变化.
- 交换反应的动力学和激活能量的确定.
主要成果:
- 界面的扩展会产生一个带有度和特性梯度的区域.
- 由两个原始网络组成的新网络.
- 通过交换反应发生细分级别的混合.
- 测量了交换反应的动力学,并确定了激活能量.
结论:
- 不同环氧网络的界面扩展导致梯度区域和新的混合网络.
- 纳米机械绘制为细分混合过程提供了洞察力.
- 该研究量化了这种混合现象的反应动力学和激活能量.
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