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相关概念视频

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Metallic Solids02:37

Metallic Solids

20.9K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.9K
Network Covalent Solids02:18

Network Covalent Solids

16.2K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.2K
Batteries and Fuel Cells03:12

Batteries and Fuel Cells

31.0K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
31.0K
Inductance: Solid Cylindrical Conductor01:24

Inductance: Solid Cylindrical Conductor

881
To calculate the inductance of a solid cylindrical conductor, consider a 1-meter section of a non-magnetic, current-carrying conductor with radius r. Disregarding end effects and assuming uniform current density, Ampere's law helps determine the magnetic field inside the conductor. This law states that the magnetic field intensity H is concentric and constant within the conductor.
Given the uniform current distribution, the magnetic field Hx and flux density Bx inside the conductor are...
881
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

72.1K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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通过离子导体层减轻阴极固体电解质的界面潜力下降,以提高固体电池的界面动力

Jia-Yan Liang1,2, Xian-Xiang Zeng3, Xu-Dong Zhang1,2

  • 1CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry , Chinese Academy of Sciences (CAS) , Beijing 100190 , P. R. China.

Journal of the American Chemical Society
|May 19, 2018
PubMed
概括
此摘要是机器生成的。

一个新的过渡层通过减少界面极化来提高固体电池的性能. 这提高了下一代高功率固体电池的循环稳定性和速度能力.

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科学领域:

  • 材料科学
  • 电化学
  • 固态电池

背景情况:

  • 固态电池面临着由于阴极电解质接触不良和界面极化而导致容量衰减的挑战.
  • 减轻这些接口问题对于实现固体电池的高功率密度至关重要.

研究的目的:

  • 引入和研究一种Li+导电过渡层,以提高固态电池的性能.
  • 了解负责改善电池动态和稳定的接口机制.

主要方法:

  • 在 LiNi0.6Co0.2Mn0.2O2 阴极上涂上 Li1.4Al0.4Ti1.6 ((PO4) 3 过渡层.
  • 使用原子力显微镜与边界电位分析来研究界面性质.

主要成果:

  • 过渡层有效地减轻了界面两极分化,提供了渐进的潜在斜率.
  • 修改后的阴极在室温下表现出更好的循环稳定性 (在100个循环后达到90%) 和优异的速率 (116 mAh g-1).

结论:

  • 开发的接口过渡层显著提高了固态电池的电化学性能.
  • 这项工作为推进未来固体电池技术提供了界面工程的见解.