通过对结构扭曲进行控制,制造石墨烯纳米带的带隙工程
Yunbin Hu1,2, Peng Xie3, Marzio De Corato4,5
1Max Planck Institute for Polymer Research , Ackermannweg 10 , D-55128 Mainz , Germany.
Journal of the American Chemical Society
|May 22, 2018
概括
在石墨烯纳米带 (GNR) 中通过基侧链引入微妙的结构扭曲可以调整它们的电子特性. 这种非平面的修改减少了带隙,为纳米电子和光电子提供了新的途径.
科学领域:
- 有机电子材料
- 纳米电子和光电子的半导体材料
背景情况:
- 石墨烯纳米带 (GNR) 具有由化学结构定义的可调节性质 (移动性,光学吸收,带隙).
- 平面GNR一直是主要的焦点,忽视了非平面性作为属性调节参数.
研究的目的:
- 研究非平面性对GNR属性的影响.
- 探索使用基侧链来诱导结构扭曲和调整电子特性.
主要方法:
- 关于GNR结构的理论研究,其中包括形边缘和变化的链位置.
- 平面和非平面GNR的实验合成和表征.
- 使用紫外线对近红外吸收和光发光激发光谱.
主要成果:
- 在最内在的边位置的链会诱导固体排斥,导致外围环曲.
- 这种结构性扭曲理论上将GNR带差缩小至0.27 eV.
- 实验结果证实了非平面GNR的理论带隙减少.
结论:
- 通过非平面性实现的微妙结构扭曲是工程GNR属性的可行方法.
- 这种方法为设计下一代半导体材料提供了一个新的参数.
- 非平面GNR为纳米电子和光电子应用提供了增强的可能性.
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