在21,1 T的K固态NMR中化佩洛夫斯基特的相分离
Dominik J Kubicki, Daniel Prochowicz1, Albert Hofstetter
1Institute of Physical Chemistry , Polish Academy of Sciences , Kasprzaka 44/52 , 01-224 Warsaw , Poland.
Journal of the American Chemical Society
|May 22, 2018
概括
在化 Perowskite 中的兴奋剂不会将纳入 Perowskite 晶格. 相反,它形成单独的富相,影响材料组成和太阳能电池性能.
科学领域:
- 材料科学
- 固态化学
- 太阳能发电
背景情况:
- 有机无机化矿是新一代太阳能电池的高效吸光剂,效率超过22%.
- 当前电压 (J-V) 歇斯底里,其中效率取决于循环历史,是矿太阳能电池的一个重大挑战.
- 兴奋剂是缓解J-V歇斯底里的一种有希望的策略,但其原子化机制尚不清楚.
研究的目的:
- 提供含阶段的第一个原子级特征 KI-doped 聚合物和多离子化矿石.
- 阐明在抑制原子尺度上的J-V歇斯底里作用.
主要方法:
- 固态核磁共振 (NMR) 光谱,特别是39K MAS NMR在21.1 T.
- 用添加化的矿样品的特征.
主要成果:
- 没有发现融入3D矿网格的证据.
- 基因组合导致富含的阶段的形成和未反应的基因组合.
- 在含有的矿中,KI合导致了KI/KBr混合物,改变了Br/I比率.
- 同时的Cs和K兴奋剂导致非矿Cs/K酸阶段.
结论:
- 兴奋剂不会将K+离子整合到矿结构中.
- 观察到的富含的阶段,而不是格子合并,是 KI 兴奋剂的影响.
- 对于优化矿太阳能电池的稳定性和性能来说, 了解这些二级阶段的形成至关重要.
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