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Fused Filament Fabrication FFF of Metal-Ceramic Components
Published on: January 11, 2019
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金属稳定型化二碳醇系统
Xian-Sheng Ke1, Yongseok Hong2, Vincent M Lynch1
1Department of Chemistry , The University of Texas at Austin , Austin , Texas 78712-1224 , United States.
Journal of the American Chemical Society
|May 23, 2018
概括
我们开发了一种金属复合的策略, 将双插入到二二碳醇联体中,产生具有独特电子和光学特性的状物种,可用于设计新材料.
科学领域:
- 有机化学
- 材料科学
- 超分子化学
背景情况:
- 多环芳 (PAH) 在材料科学中至关重要.
- 扩展和它们的金属复合物具有可调节的电子性质.
- 开发具有特定光学特性的稳定型PAH仍然是一个挑战.
研究的目的:
- 开发一种金属复合策略,用于合成稳定,形PAH衍生物.
- 研究一种新型双金属扩展的电子和光学特性.
- 探索金属化对细调联体电子特征的潜力.
主要方法:
- 一个二[g,p]烯融合的二甲基联体的合成.
- 双插入 (II) 离子形成双金属化复合物.
- 使用NMR光谱,EPR,X射线晶体学,拉曼光谱和计算方法 (HOMA,NICS) 的表征.
主要成果:
- 合成了一种稳定的双金属化复合物 (bis-Pd),表现为形性质.
- 在 bis-Pd 复合体的最低能量吸收波段显示出显著的红移到 NIR 区域 (1420 nm).
- 谱学和计算分析证实了 bis-Pd 系统的形性质和封闭外电子结构,并有证据表明它具有电共振.
结论:
- 金属复合提供了稳定的形PAH的有效途径.
- 该 bis-Pd 复合体表现出可调节的电子和光学特性,包括强烈的溶色.
- 这种方法提供了一个可通用的策略,用于设计具有针对高级应用的长波长吸收的新型形PAH.
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