可预测粒子工程:编程核心外粒子的能量水平,载体生成和导电性
Journal of the American Chemical Society
|May 25, 2018
概括
研究人员通过涂覆半导体纳米晶体与酸聚合物外来开发可编程的核心外纳米粒子. 这提高了电气性能,为先进的复合材料提供了多功能策略.
科学领域:
- 材料科学
- 纳米技术
- 聚合物化学
背景情况:
- 核心外结构对于纳米级复合材料至关重要,可使组件之间产生协同效应.
- 核心和外的有效设计是实现这些结构的全部潜力的关键.
研究的目的:
- 使用半导体纳米晶体和酸聚合物外实现可编程核心外相互作用的方法.
- 研究这些相互作用对产生的复合粒子电子特性的影响.
主要方法:
- 用酸聚合物外装饰半导体纳米晶体 (ZnO,TiO2).
- 采用甲基表面结合和B-N基结合作为形成的驱动力.
- 控制和预测可调节属性的外厚度.
主要成果:
- 核心外相互作用缩小了半导体纳米晶体的带隙,并改变了聚合物外的HOMO/LUMO水平.
- 观察到载体密度和孔移动性的显著改善 (高达9个数量级).
- 与原始纳米晶体相比, 导电性增加了30倍.
结论:
- 开发的粒子工程策略可以实现可预测的外厚度的可编程核心外相互作用.
- 这种方法是多功能且适用于各种无机纳米粒子,促进了先进的复合材料的制造.
相关概念视频
The Nucleosome Core Particle
14.6K
Nucleosomes are the DNA-histone complex, where the DNA strand is wound around the histone core. The histone core is an octamer containing two copies of H2A, H2B, H3, and H4 histone proteins.
The paradox
Nucleosomes, paradoxically, perform two opposite functions simultaneously. On the one hand, their main responsibility is to protect the delicate DNA strands from physical damage and help achieve a higher compaction ratio. While on the other hand, they must allow polymerase enzymes to access DNA...
The paradox
Nucleosomes, paradoxically, perform two opposite functions simultaneously. On the one hand, their main responsibility is to protect the delicate DNA strands from physical damage and help achieve a higher compaction ratio. While on the other hand, they must allow polymerase enzymes to access DNA...
14.6K
The Nucleosome Core Particle
2.4K
Nucleosomes are the DNA-histone complex, where the DNA strand is wound around the histone core. The histone core is an octamer containing two copies of H2A, H2B, H3, and H4 histone proteins.
Nucleosomes, paradoxically, perform two opposite functions simultaneously. On the one hand, their primary aim is to protect the delicate DNA strands from physical damage and help achieve a higher compaction ratio. On the other hand, they must allow polymerase enzymes to access histone-bound DNA during...
Nucleosomes, paradoxically, perform two opposite functions simultaneously. On the one hand, their primary aim is to protect the delicate DNA strands from physical damage and help achieve a higher compaction ratio. On the other hand, they must allow polymerase enzymes to access histone-bound DNA during...
2.4K
Basic Postulates of Kinetic Molecular Theory: Particle Size, Energy, and Collision
37.9K
The ideal-gas equation, which is empirical, describes the behavior of gases by establishing relationships between their macroscopic properties. For example, Charles’ law states that volume and temperature are directly related. Gases, therefore, expand when heated at constant pressure. Although gas laws explain how the macroscopic properties change relative to one another, it does not explain the rationale behind it.
37.9K
Subatomic Particles
113.6K
Dalton was only partially correct about the particles that make up matter. All matter is composed of atoms, and atoms are composed of three smaller subatomic particles: protons, neutrons, and electrons. These three particles account for the mass and the charge of an atom.
113.6K
Electron Carriers
92.0K
Electron carriers can be thought of as electron shuttles. These compounds can easily accept electrons (i.e., be reduced) or lose them (i.e., be oxidized). They play an essential role in energy production because cellular respiration is contingent on the flow of electrons.
Over the many stages of cellular respiration, glucose breaks down into carbon dioxide and water. Electron carriers pick up electrons lost by glucose in these reactions, temporarily storing and releasing them into the electron...
Over the many stages of cellular respiration, glucose breaks down into carbon dioxide and water. Electron carriers pick up electrons lost by glucose in these reactions, temporarily storing and releasing them into the electron...
92.0K
Carrier Generation and Recombination
1.3K
Carrier generation is the process by which electron-hole pairs (EHPs) are created within the semiconductor. In direct-bandgap semiconductors, such as gallium arsenide (GaAs), this occurs efficiently when energy absorption prompts valence electrons to leap into the conduction band, leaving behind holes.
This process is given by the generation rate G and is efficient due to the conservation of momentum between the valence band maximum and conduction band minimum.
Indirect generation involves an...
This process is given by the generation rate G and is efficient due to the conservation of momentum between the valence band maximum and conduction band minimum.
Indirect generation involves an...
1.3K


