探索共价有机框架的应用:用于动态核极化的基质的同质网络
Wei Cao1, Wei David Wang1, Hai-Sen Xu1
1State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering , Lanzhou University , Lanzhou , Gansu 730000 , China.
Journal of the American Chemical Society
|May 26, 2018
概括
嵌入激素的共价有机框架 (COF) 作为动态核极化 (DNP) NMR 的有效极化剂. 这些激进的COF为各种核提供了增强的信号强度.
科学领域:
- 材料科学
- 化学学
- 核磁共振 (NMR) 光谱学
背景情况:
- 共价有机框架 (COF) 是具有可调节结构的晶体多孔聚合物.
- 动态核极化 (DNP) 通过电子核极化转移增强NMR信号强度.
- 有效的DNP需要对不对的电子 (激素) 的均分布和固定方向.
研究的目的:
- 构建根嵌入COFs (PR(x) -COFs) 用作DNP极化剂.
- 研究PR(x) -COFs在增强NMR信号强度方面的功效.
- 探索COF作为新型DNP剂的应用.
主要方法:
- 使用自下而上的策略合成基嵌入COFs (PR(x) -COFs.
- 在晶体,中孔性COF框架中对基的共价结合.
- 在DNP增强的固态NMR实验中应用PR(x) -COF.
主要成果:
- 成功构建具有均分布和刚性嵌入基的PR(x) -COF.
- 对1H,13C和15N固态NMR显著增强DNP.
- 在COF框架内达到可调节的基度 (x%).
结论:
- 根嵌入的COF是DNP NMR的有效偏振剂.
- 在DNP应用中,COF可以作为"晶体海绵".
- 这项工作为合理设计的COF作为标准DNP剂的利用铺平了道路.
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