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相关概念视频

Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Covalent Bonds01:29

Covalent Bonds

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Overview
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Covalent Bonds01:08

Covalent Bonds

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When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
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Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
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Proteins can undergo many types of post-translational modifications, often in response to changes in their environment. These modifications play an important role in the function and stability of these proteins. Covalently linked molecules include functional groups, such as methyl, acetyl, and phosphate groups, and also small proteins, such as ubiquitin. There are around 200 different types of covalent regulators that have been identified.
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Common Ion Effect03:24

Common Ion Effect

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Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Châtelier’s principle. Consider the dissolution of silver iodide:
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Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
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在聚电解质共价有机框架中的离子导电

Qing Xu1, Shanshan Tao1, Qiuhong Jiang1

  • 1Department of Chemistry, Faculty of Science , National University of Singapore , 3 Science Drive 3 , Singapore 117543 , Singapore.

Journal of the American Chemical Society
|May 30, 2018
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此摘要是机器生成的。

研究人员开发了多电解质共价有机框架 (COF) 以提高离子导电性. 这项创新显著提高了固态电解质中的离子传输.

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科学领域:

  • 材料科学
  • 电化学
  • 纳米技术

背景情况:

  • 共价有机框架 (COF) 具有适合离子传输的有序1D通道.
  • 在赤裸的COF通道中,有限的离子导电性阻碍了它们在固态电解质中的应用.

研究的目的:

  • 通过使用氧化乙烯链使孔壁功能化,设计聚电解质共价有机框架 (COF).
  • 增强COF纳米通道中的离子传输和导电性.

主要方法:

  • 在COF的孔壁上集成柔性氧化乙烯链.
  • 离子与COF纳米通道中的工程聚电解质接口的复合.

主要成果:

  • 在离子复合后在COF纳米通道内形成多电解质接口.
  • 与裸体COF相比,离子导电性的增强超过3个数量级.
  • 通过改善循环和热稳定的载体机制促进离子运动.

结论:

  • 在COF的1D纳米通道中设计多电解质接口是固态离子导体的可行策略.
  • 多电解质COF为具有高离子导电性的先进固态电解质提供了有前途的途径.
  • 这种方法为开发高性能固态电池和电化学设备开辟了新的途径.