超分子囊泡和纳米纤维的可逆自组合由素结合相互作用驱动
Liang Chen1, Jun Xiang2, Yue Zhao2
1Key Laboratory of Molecular Engineering of Polymers , Fudan University , Shanghai 200433 , China.
Journal of the American Chemical Society
|May 30, 2018
概括
研究人员利用基键 (Te·O或Se·O) 制造出新的超基. 这些分子自组合成超分子囊泡和纳米纤维,为超分子化学提供了新的可能性.
科学领域:
- 超分子化学
- 材料科学
- 化学物理
背景情况:
- 素结合是一种新兴的非共价相互作用.
- 对于分子自组合的素键的利用在很大程度上仍未被探索.
研究的目的:
- 报告第一个由素结合驱动的超两细胞.
- 研究这些新型分子自组成纳米结构的过程.
主要方法:
- 准质[4]甲基 (C4Ch) 宏循环供体的设计
- 作为分子接受剂的尾状氧化表面活性剂的设计.
- 通过Te·O或Se·O基键形成捐赠体-接受体复合体.
主要成果:
- 通过素结合相互作用成功形成新型超两细胞.
- 自组装成超分子囊泡和纳米纤维的演示.
- 控制纳米结构的几何,由素键亲和力决定.
结论:
- 碳酸键可以有效地驱动超的形成.
- 通过调整素结合相互作用,可以实现多种自组装纳米结构.
- 通过竞争性离子或pH值变化可以实现纳米结构的可逆分解.
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