纳米结构混合金属氧化物的高效氧气电催化
Xiang-Kui Gu1, Juliana S A Carneiro1, Samji Samira1
1Department of Chemical Engineering and Materials Science , Wayne State University , Detroit , Michigan 48202 , United States.
Journal of the American Chemical Society
|May 31, 2018
概括
研究人员使用混合金属氧化物开发了高效的氧气电催化设计原理. 在燃料电池中,纳米结构的配合氧化具有高活性和稳定性.
科学领域:
- 材料科学
- 电化学
- 能源转化和储存
背景情况:
- 氧气电催化对于能源系统至关重要,
- 混合金属氧化物具有可调的表面和快速的氧气导电性.
- 有层的Ruddlesden-Popper (R-P) 氧化物对氧气电催化有希望.
研究的目的:
- 在R-P氧化物中开发氧气电催化工程的设计原理.
- 识别氧降解反应 (ORR) 的高效电催化剂.
- 使用新型催化剂提高固体氧化燃料电池 (SOFC) 的性能.
主要方法:
- 结合理论 (密度函数理论 - DFT) 和实验研究.
- 使用的DFT衍生描述符:表面氧空位上的O2结合能量.
- 采用纳米结构RP氧化物的受控合成,并通过热化学/电化学研究进行验证.
主要成果:
- DFT描述器有效地确定了ORR的高效R-P氧化物结构.
- 纳米结构配合氧化显示出高ORR活性.
- 将SOFC纳入阴极显著提高了在中间温度 (550°C) 的性能,并具有长期稳定性.
结论:
- 开发的设计原理有效地设计混合离子电子导电氧化物用于氧气电催化.
- 纳米结构配合氧化是氧气电催化剂的非常有前途的催化剂.
- 这些发现有助于设计高效的电催化剂用于能源应用.
相关概念视频
Oxidation Numbers
42.9K
In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the oxidation number (or oxidation state). It represents the effective charge of an atom or element, which is assigned using a set of rules.
42.9K
Metal-Ligand Bonds
24.4K
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
24.4K
Alkali Metals
24.9K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
24.9K
Metallic Solids
20.8K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.8K
Properties of Transition Metals
30.0K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
30.0K
Oxidation-Reduction Reactions
75.8K
Oxidation–Reduction Reactions
75.8K


