石墨烯模板垂直甲纳米柱的相位过渡
D Leonardo Gonzalez Arellano1, Edmund K Burnett1, Sema Demirci Uzun1
1Department of Polymer Science and Engineering , University of Massachusetts Amherst , Amherst , Massachusetts 01003 , United States.
Journal of the American Chemical Society
|June 8, 2018
概括
我们开发了一种方法来控制甲 (ZnPc) 单晶纳米柱中的分子包装. 这允许在不改变纳米结构的情况下增强气体传感器性能
科学领域:
- 材料科学
- 纳米技术
- 晶体学
背景情况:
- 在气体传感应用中,甲 (ZnPc) 单晶纳米柱是有前途的.
- 控制分子包装对于优化设备性能至关重要.
- 现有的方法经常改变纳米结构形态.
研究的目的:
- 研究ZnPc单晶纳米柱的石墨烯辅助生长和相位过渡.
- 通过后结晶化来探索形态-保留性相位过渡.
- 通过受控的分子包装来提高气体传感器的性能.
主要方法:
- 用石墨烯辅助合成ZnPc纳米柱.
- 结晶后的热化用于相位过渡.
- 牧场发生率X射线衍射和高分辨率TEM进行表征.
- 化学电阻气体传感器的制造和测试
主要成果:
- 实现垂直导向的单晶ZnPc纳米柱.
- 通过回火证明了从转移稳定到β-阶段的形态保留性阶段过渡.
- 在β相纳米柱体中观察到由于优化分子方向而提高的氨气灵敏度.
- ZnPc纳米柱式传感器显示出对氨气蒸汽的选择性.
结论:
- 有机单晶纳米柱中的形态-保留相过渡的第一份报告.
- 在没有显著的形态变化的情况下,热提供了分子包装控制的途径.
- 这种方法对于开发高性能有机电子设备和理解结构属性关系至关重要.
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