推动金属有机框架作为催化剂支持的极限:NU-1000支持的催化剂用于o-xylen异构和不成比例
Sol Ahn, Scott L Nauert, Cassandra T Buru
1Department of Chemistry, Faculty of Science , King Abdulaziz University , Jeddah 21589 , Saudi Arabia.
Journal of the American Chemical Society
|June 19, 2018
概括
这项研究表明,酸 (PTA) 在NU-1000金属有机框架 (MOF) 中有效催化氧基烯异构. 封闭的结构允许独特的转甲基化途径,展示了用于先进碳化合物加工的MOF.
科学领域:
- 催化剂
- 材料科学
- 石油化学
背景情况:
- 酸催化骨C-C键异构在石化行业中至关重要.
- 氧氧烯异构化/不成比例化是强Brønsted酸催化的一个关键探针,对催化剂结构是敏感的.
研究的目的:
- 为了研究基酸 (PTA) 的催化活性,它被封装在NU-1000金属有机框架 (MOF) 中,用于oxylene异构化.
- 在反应条件下评估MOF封闭所带来的稳定性和独特反应性.
主要方法:
- 用PTA加载的NU-1000MOF催化剂的合成
- 使用扩展式X射线吸收精细结构 (EXAFS),31P NMR,N2物理吸收和X射线衍射 (XRD) 的表征.
- 在523K时对o-xylen异构的催化试验.
主要成果:
- 用PTA封装的NU-1000催化剂在反应条件下表现出结构稳定性,特别是在最大PTA负载下.
- 确定WOx集群对催化活性至关重要.
- 在NU-1000的封闭环境中促进了转甲基化途径的异常活动,需要相邻的活性位点.
结论:
- 金属有机框架拓可以为碳化合物异构化等具有挑战性的反应提供独特的反应能力.
- 保持催化剂的结构完整性至关重要.
- 对于设计具有定制反应性的先进催化剂,NU-1000 MOF框架提供了一个有前途的平台.
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