在CO2化金属有机框架中的过渡金属催化剂的开口封装
Zhehui Li1, Thomas M Rayder1, Lianshun Luo2
1Department of Chemistry , Boston College , Chestnut Hill , Massachusetts 02467 , United States.
Journal of the American Chemical Society
|June 19, 2018
概括
研究人员使用一种新的开口方法在金属有机框架 (MOF) 中封装了催化剂. 这种MOF封装的催化剂有效地将二氧化碳转化为酸盐,并可回收利用,为同质催化剂提供稳定的替代品.
科学领域:
- 材料科学
- 催化剂
- 化学学
背景情况:
- 金属有机框架 (MOF) 为宿主-客人化学提供可调节的多孔结构.
- 复合物是活跃的催化剂,但在同质催化过程中经常出现不稳定性和不良回收性.
研究的目的:
- 在MOF中开发一种用于封装复合物的新方法.
- 评估MOF封装的二氧化碳催化剂的催化性能和稳定性.
主要方法:
- 在基于的MOF UiO-66中进行分离链接交换,以创建开放的孔径.
- 在UiO-66框架内封装复合物 (2,6-bis((di- tert-butyl-phosphino) methyl) pyridine) Ru ((CO) HCl.
- 测试[Ru]@UiO-66材料的催化活性和可回收性,以形成二氧化碳.
主要成果:
- 封装的复合物[Ru]@UiO-66显示出高化活性.
- [Ru]@UiO-66催化剂成功回收了五次,没有显著的活性损失.
- 与其同质对应物相比,MOF封装的催化剂表现出增强的稳定性,没有双分子分解的证据,并且对催化剂中毒的敏感性降低.
结论:
- 在MOF中,孔径开放过程为合成强大的宿主-客催化材料提供了有效的策略.
- MOF封装显著提高了二氧化碳转化中的催化剂的稳定性和可回收性.
- 这项工作突显了基于MOF的材料在先进化学催化中的潜力.
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