用于高效的固态光子上转换的捐赠器-接受器-采集器三元晶体膜
Taku Ogawa1, Masanori Hosoyamada1, Brett Yurash2
1Department of Chemistry and Biochemistry, Faculty of Engineering , Center for Molecular Systems (CMS) , Kyushu University , Moto-oka 744 , Nishi-ku , Fukuoka 819-0395 , Japan.
Journal of the American Chemical Society
|June 26, 2018
概括
这项研究引入了一种使用单片能量采集器的新型固态光子上转换方法. 这种方法提高了能量传输效率,并使光量子产量增加了一倍,从而获得更好的可再生能源设备.
科学领域:
- 材料科学
- 摄影化学
- 可再生能源
背景情况:
- 固态光子上升转换 (TTA-UC) 对可再生能源至关重要,但由于染色体聚合和反向能量转移,效率受到限制.
- 固体材料中的低光量子产量阻碍了TTA-UC设备的潜力.
研究的目的:
- 通过引入高光单体能量收集器来克服固态TTA-UC的局限性.
- 实现双重能源迁移 (三重和单重) 以提高转换效率.
主要方法:
- 使用自旋涂层制造的捐赠剂受体晶膜.
- 将Pt(II) 八甲基氨酸 (PtOEP) 作为三倍体供体和2,5,8,11-四甲基氨酸 (TTBP) 作为单次体能量采集器.
- 激子扩散和能量转移动态的表征.
主要成果:
- 在纳米纤维受体晶体中达到~37nm的有效单片激子扩散.
- 两倍的固态光量子产量达到76%只有0.5%的TTBP.
- 通过隔离捐赠分子和采集分子来抑制单子反向能量传递.
- 将转换效率提高到9.0%.
结论:
- 采用单个能量采集器和双重能量迁移开发的方案显著提高了固态TTA-UC的效率.
- 建立了高效固态升级器的合理设计原则.
- 这种方法为先进的可再生能源技术提供了有前途的途径.
相关概念视频
Structures of Solids
18.0K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
18.0K
Molecular and Ionic Solids
20.2K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
20.2K
Network Covalent Solids
16.2K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.2K
Metallic Solids
20.8K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.8K
Polymer Classification: Crystallinity
4.0K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
4.0K
Molecular Comparison of Gases, Liquids, and Solids
55.4K
Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
55.4K


