通过微妙的变化控制定向超分子组件的多功能控制
Alan Kwun-Wa Chan1, Maggie Ng1, Kam-Hung Low1
1Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants Committee, Hong Kong) and Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , P.R. China.
Journal of the American Chemical Society
|June 27, 2018
概括
使用CF3替代剂的 (I) 复合物表现出增强的稳定性和自组装性. 这些复合物形成有序的结构,揭示了非共价相互作用的洞察力,并导致了新的超分子材料.
科学领域:
- 协调化学
- 超分子化学
- 材料科学
背景情况:
- (I) 复合体表现出由Rh (I) ··Rh (I) 相互作用驱动的自我组装.
- 像CF3这样的取电子替代剂可以增强复杂的稳定性和定向组装.
研究的目的:
- 研究 (I) 复合体自组合中的非共价相互作用.
- 了解管理分子间相互作用的结构属性关系.
- 探索螺旋式超分子组合的形成.
主要方法:
- 合成各种具有不同结构特征的 (I) .
- 加入吸收电子的CF3替代剂.
- 介绍螺旋组件的合辅助器件.
主要成果:
- 确定了溶剂诱导聚合的异体生长机制.
- 在聚合物种 (二聚体,三聚体,寡聚体) 中观察到强烈的低能量吸收带.
- 通过使用奇拉辅助器证明了螺旋式超分子组件和软材料的形成.
结论:
- CF3替代剂提高了I复合物的稳定性和定向组装.
- 自组装行为由非共价相互作用和联体电子性质控制.
- 化 (I) 复合物使得先进的超分子结构的构建成为可能.
相关概念视频
Movement Joints in Buildings
358
Movement joints in buildings are essential design elements that accommodate inevitable motions caused by various factors such as temperature changes, moisture content variations, and structural deflections. These motions, if not considered in design and construction, can lead to unsightly or dangerous damage. Movement joints are incorporated in different forms to manage these stresses and allow materials to move without causing distress.
The simplest type of movement joints, working joints, are...
The simplest type of movement joints, working joints, are...
358
Types of Building Stone
457
Building stones, essential materials for construction, are extracted from natural rock deposits and processed into specific forms and dimensions suitable for various building applications. These stones are broadly classified into three types based on their geological formation: igneous, sedimentary, and metamorphic.
Igneous rocks are formed from the solidification of magma or lava. An example is granite, known for its durability and resistance to weathering, making it ideal for parts of...
Igneous rocks are formed from the solidification of magma or lava. An example is granite, known for its durability and resistance to weathering, making it ideal for parts of...
457
Protein Complex Assembly
16.8K
Proteins can form homomeric complexes with another unit of the same protein or heteromeric complexes with different types. Most protein complexes self-assemble spontaneously via ordered pathways, while some proteins need assembly factors that guide their proper assembly. Despite the crowded intracellular environment, proteins usually interact with their correct partners and form functional complexes.
Many viruses self-assemble into a fully functional unit using the infected host cell to...
Many viruses self-assemble into a fully functional unit using the infected host cell to...
16.8K
Block Diagram Reduction
567
The process of deriving the transfer function of a control system often involves reducing its block diagram to a single block. This simplification can be achieved through a series of strategic operations, including relocating branch points and comparators. These operations preserve the overall function of the system while allowing for easier manipulation and combination of blocks.
The first step in this process is the identification and relocation of a branch point. A branch point, where a...
The first step in this process is the identification and relocation of a branch point. A branch point, where a...
567
Types of Building Separation Joints
631
Building separation joints divide large or complex building structures into smaller, discrete units that can move independently. These joints are categorized into three types: volume-change joints, settlement joints, and seismic separation joints.
Volume-change joints address the effects of expansion and contraction due to temperature and moisture variations. They are strategically placed at discontinuities in a building's mass where cracking is most likely and are spaced about 150 to 200...
Volume-change joints address the effects of expansion and contraction due to temperature and moisture variations. They are strategically placed at discontinuities in a building's mass where cracking is most likely and are spaced about 150 to 200...
631
Design Example: Sustainability in Concrete Building
424
As the construction industry moves towards more eco-friendly practices, concrete's adaptability and its ability to incorporate sustainable features make it a key material in the drive towards greener building solutions.
There are multiple approaches to achieve sustainability in a commercial concrete building. For instance, construct a concrete parking area under the building, utilizing pervious concrete paver blocks in open areas to facilitate rainwater collection through an underground...
There are multiple approaches to achieve sustainability in a commercial concrete building. For instance, construct a concrete parking area under the building, utilizing pervious concrete paver blocks in open areas to facilitate rainwater collection through an underground...
424


