通过侧链工程进行形态优化,使全聚合物太阳能电池具有出色的填充因子和稳定性
Xi Liu1,2, Chaohong Zhang3, Chunhui Duan1
1Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices , South China University of Technology , Guangzhou 510640 , People's Republic of China.
Journal of the American Chemical Society
|June 27, 2018
概括
研究人员使用工程聚合物开发了全聚合物太阳能电池. 这一策略改善了纳米尺度的形态,从而提高了聚合物:聚合物混合物的功率转换效率 (PCE) 和稳定性.
科学领域:
- 材料科学
- 有机电子
- 聚合物化学
背景情况:
- 全聚合物太阳能电池 (全PSC) 在批量异质连接中使用合聚合物.
- 在聚合物:聚合物混合物中实现最佳形态仍然是所有PSC性能的一个重大挑战.
研究的目的:
- 开发一种用于优化全PSC纳米规模组织的新战略.
- 设计基于二甲胺 (NDI) 的聚合物受体,以提高性能和稳定性.
主要方法:
- 基于NDI的聚合物N2200的侧链工程通过引入线性氧化 (OE) 链.
- 一系列基于NDI的聚合物受体 (NOE x) 的合成,含有不同的OE.
主要成果:
- 使用10%OE链置换的NOE10聚合物实现了8.1%的功率转换效率和0.75的填充系数.
- 基于NOE10的所有PSC显示出优异的长期和热稳定性,在65°C下300小时后保留超过97%的初始PCE.
结论:
- 侧链工程是所有PSC形态优化的有效策略.
- 在所有PSC中,NOE10聚合物具有显著的潜力,可以作为高性能,稳定的替代现有受体聚合物.
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