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相关概念视频

Diffusion01:12

Diffusion

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Diffusion is the passive movement of substances down their concentration gradients—requiring no expenditure of cellular energy. Substances, such as molecules or ions, diffuse from an area of high concentration to an area of low concentration in the cytosol or across membranes. Eventually, the concentration will even out, with the substance moving randomly but causing no net change in concentration. Such a state is called dynamic equilibrium, which is essential for maintaining overall...
220.2K
Diffusion01:21

Diffusion

6.4K
Diffusion is a type of passive transport. In passive transport, a substance tends to move from an area of high concentration to an area of low concentration until the concentration is equal across the space. For example, take the diffusion of substances through the air. When someone opens a perfume bottle in a room filled with people, the perfume is at its highest concentration in the bottle and is at its lowest at the edges of the room. The perfume vapor will diffuse, or spread away, from the...
6.4K
Standard Electrode Potentials03:02

Standard Electrode Potentials

50.4K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
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Drugs Affecting GI Tract Motility: Adsorbents as Antidiarrheal Agents01:20

Drugs Affecting GI Tract Motility: Adsorbents as Antidiarrheal Agents

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Diarrhea is characterized by the occurrence of frequent, watery bowel movements. Various factors can trigger diarrhea, including viral or bacterial infections, foodborne illnesses, side effects from certain medications, and underlying digestive disorders. If not adequately managed, diarrhea can lead to complications such as dehydration, electrolyte imbalances, and nutrient deficiencies. Severe diarrhea can lead to significant weight loss, malnutrition, and weakened immune function.
Adsorbents...
635
Facilitated Diffusion01:16

Facilitated Diffusion

1.3K
The plasma membrane, a critical structure in cellular biology, houses an array of transporters, or carrier proteins, interspersed within its lipid bilayer. These proteins play a crucial role in solute transport through facilitated diffusion, a form of passive diffusion that uses transporters to move the molecules across the membrane.
In this process, substrates such as organic compounds and ions interact with a transporter on one side, triggering conformational changes in proteins that enable...
1.3K
Electrodes: Overview01:17

Electrodes: Overview

2.7K
 Electrochemical measurements are conducted in an electrochemical cell composed of various components that control and measure the current and potential. One fundamental component is electrodes, conductive materials that enable electron transfer reactions at their surfaces.
There are two main types of electrodes in electrochemical cells. The first type, known as the working or indicator electrode, has a potential that is sensitive to the analyte's concentration and reacts to changes in...
2.7K

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相关实验视频

Updated: Feb 8, 2026

Pore-scale Imaging and Characterization of Hydrocarbon Reservoir Rock Wettability at Subsurface Conditions Using X-ray Microtomography
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Pore-scale Imaging and Characterization of Hydrocarbon Reservoir Rock Wettability at Subsurface Conditions Using X-ray Microtomography

Published on: October 21, 2018

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在电极上形成和扩散地表吸附物

Björn Rahn1, Olaf M Magnussen1

  • 1Institute of Experimental and Applied Physics , Kiel University , Olshausenstrasse 40 , 24098 Kiel , Germany.

Journal of the American Chemical Society
|July 10, 2018
PubMed
概括

研究人员观察到地下物种在金属电极上形成,并在表面层中迁移. 这一发现使用扫描道显微镜,通过空隙介导途径显示了增强的表面扩散,可能会影响电催化.

科学领域:

  • 表面科学
  • 电化学
  • 材料科学

背景情况:

  • 了解金属电极的界面过程对于电催化是至关重要的.
  • 电极表面层中的物种动态尚未完全理解.
  • 电化学双层会影响表面反应.

研究的目的:

  • 在金属电极上直接观察地下物种的形成和迁移.
  • 研究表面空缺在物种扩散中的作用.
  • 探索增强的表面动力学对电催化反应的影响.

主要方法:

  • 在现场视频速率扫描道显微镜 (STM).
  • 在液体电解质中的覆盖的Ag100) 电极上研究了吸附硫化物.
  • 分析了表面吸附点和地下空隙之间的可逆过渡.

主要成果:

  • 在电化学双层下直接观察地下物种的形成和迁移.
  • 在表面位置和第一层Ag空隙之间确定了吸附硫化物的可逆过渡.
  • 在硫化物表面扩散中观察到的数量级增强归因于空隙介导的途径.

结论:

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  • 地下物种的形成和迁移是金属电极表面发生的动态过程.
  • 空隙介导的扩散显著提高了表面物种的流动性.
  • 这些发现表明了电催化反应和物质生长过程的新途径.