佩罗夫斯基特纳米晶体的兴奋剂增强的短距离顺序,用于近单位的紫色发光量产量
Zi-Jun Yong1, Shao-Qiang Guo2, Ju-Ping Ma1
1College of Chemistry, Chemical Engineering and Materials Science , Soochow University , Jiangsu , 215123 , China.
Journal of the American Chemical Society
|July 17, 2018
概括
离子兴奋剂通过改善晶格秩序和减少缺陷来增强全无机紫色发射的晶 (NCs). 这一突破为先进的光电子应用实现了近单位的光发光量子产量 (PLQY).
科学领域:
- 材料科学
- 纳米技术
- 固态物理
背景情况:
- 全无机矿纳米晶 (NC) 提供低成本的半导体发光材料.
- 在绿色和红色的光谱范围实现了高光发光量子产量 (PLQY),但紫色的发射仍然很差.
- 对于光电子应用来说,了解紫色发射矿NC的局限性至关重要.
研究的目的:
- 开发一种高PLQY的全无机紫色发射矿NCs的合成策略.
- 调查紫色发射矿NC的晶格顺序和性能缺陷的作用.
- 为了实现基于矿的高效紫外线发射光电子设备.
主要方法:
- 使用 (Ni) 离子合的全无机酸盐合成.
- 使用稳定状态和时间分辨率的发光光谱学进行表征.
- 对X射线吸收光谱和旋转角核磁共振光谱的分析.
- 密度函数理论 (DFT) 计算以了解缺陷形成和电子性质.
主要成果:
- 在矿NC中使用状局部顺序.
- 消除内在缺陷,例如化物空缺,导致短距离格子秩序增加.
- 对于紫色发射矿的近单位PLQYs的演示.
- DFT的计算证实了Ni注增加了缺陷形成能量,并避免了深陷状态.
结论:
- 由内在缺陷引起的短距离晶格障碍限制了紫色发射矿的PLQY.
- 胺可以有效地增强局部格子秩序,并将PLQY提升到接近单元的水平.
- 这种进步有助于开发高性能紫外线发射的矿光电子设备.
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