共价有机框架-共价有机框架双层膜用于高度选择性气体分离
Hongwei Fan1,2, Alexander Mundstock1, Armin Feldhoff1
1Institute of Physical Chemistry and Electrochemistry , Leibniz Universität Hannover , Callinstraße 3A , D-30167 Hannover , Germany.
Journal of the American Chemical Society
|July 19, 2018
概括
使用两种类型的共价有机框架 (COF) 的新复合膜提供了优异的气体分离. 这种COF-COF双层膜对H2/CO2等混合物具有增强的选择性,超过了以前的基准值.
科学领域:
- 材料科学
- 化学工程
- 纳米技术
背景情况:
- 由于其稳定性,共价有机框架 (COF) 对分子选膜具有前景.
- 开发具有精确控制,小孔的COF膜对于有效的气体分离至关重要.
研究的目的:
- 创建一种具有增强气体分离能力的新型COF-COF复合膜.
- 研究由COF-LZU1和ACOF-1组成的双层膜的性能.
主要方法:
- 在多孔支上合成了二维层叠COF-COF复合膜.
- 采用温度波动的溶热方法,逐渐生长基于 imine 的 COF-LZU1 和基于 azine 的 ACOF-1 层.
- 对H2/CO2,H2/N2和H2/CH4混合物的评估气体分离性能.
主要成果:
- 与单个COF膜相比,COF-LZU1-ACOF-1双层膜具有显著更高的分离选择性.
- 增强的性能归因于双层结构内交织的孔隙网络的形成.
- 复合膜的性能超过了已确定的Robeson气体分离上限.
结论:
- 开发的COF-LZU1-ACOF-1双层膜代表了分子选技术的重大进步.
- 这种膜具有很好的选择性,并且超过性能极限,这表明它在工业气体分离应用中的潜力.
- 复合膜还具有很高的热稳定性和长期运行稳定性.
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