有色单壁碳纳米管薄膜的直接合成
Yongping Liao1, Hua Jiang1, Nan Wei1
1Department of Applied Physics , Aalto University School of Science , P.O. Box 15100, FI-00076 Aalto , Finland.
Journal of the American Chemical Society
|July 28, 2018
概括
研究人员通过在浮动催化剂化学蒸汽沉积 (FC-CVD) 过程中添加二氧化碳来合成可调色颜色和度的单壁碳纳米管 (SWCNT). 这种方法为生产用于电子应用的SWCNT提供了新的途径.
科学领域:
- 材料科学
- 纳米技术
- 化学工程
背景情况:
- 通过浮动催化剂化学蒸汽沉积 (FC-CVD) 在单壁碳纳米管 (SWCNT) 中实现受控的度分布仍然是一个重大挑战.
- 调节SWCNT属性对于其在先进电子中的应用至关重要.
研究的目的:
- 开发一种可调整的度分布和颜色的SWCNT片合成方法.
- 研究二氧化碳添加对FC-CVD中的SWCNT合成的影响.
主要方法:
- 使用浮动催化剂化学蒸汽沉积 (FC-CVD) 以一氧化碳 (CO) 为碳来源.
- 将不同数量的二氧化碳 (CO2) 引入FC-CVD反应器.
- 优化反应器温度以控制SWCNT直径和度.
主要成果:
- 具有可调整的度分布和明显颜色 (观察到绿色和棕色) 的SWCNT膜的直接合成.
- 达到了一个狭窄的度分布,集在 (11,9) 周围,SWCNT的直径从1.2到1.5nm (>98%).
- 建议CO2影响CO不成比例和SWCNT核化,影响直径.
结论:
- 添加二氧化碳为直接合成具有可控度和直径的SWCNT提供了一条新途径.
- 这种方法有助于生产具有特定性能的SWCNT,用于触摸传感器和晶体管等电子领域的潜在应用.
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