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从电子转移到能量转移之间的pH驱动的机械切换[Ru(bpy) 3和铁素衍生物

Claire Drolen1, Eric Conklin1, Stephen J Hetterich1

  • 1Department of Chemistry , Amherst College , Merrill Science Building , Amherst , Massachusetts 01002 , United States.

Journal of the American Chemical Society
|August 3, 2018
PubMed
概括

质子可用性决定了三 (二) 激发状态如何与水中的铁衍生物相互作用. 火机制根据pH值在能量和电子转移之间切换, 显示复杂的失活路径.

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