结合微孔聚合物的能量带隙工程通过依赖酸度的现场循环
Jiyoung Lee1, Onur Buyukcakir1, Tae-Woo Kwon1
1Graduate School of Energy, Environment, Water, and Sustainability (EEWS) , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , Republic of Korea.
Journal of the American Chemical Society
|August 10, 2018
概括
这项研究引入了一种无金属的方法,用于制造具有可调节光带间隙的合微孔聚合物 (CMP). 新方法使用酸催化剂精确控制CMP特性,避免贵金属.
科学领域:
- 材料科学
- 聚合物化学
- 纳米技术
背景情况:
- 结合微孔聚合物 (CMP) 将 π 结合的骨干与多孔网络集成为电荷和物质传输.
- 调整CMP电子属性传统上涉及单体变化,并且需要C-C合的贵金属催化剂.
研究的目的:
- 为CMP开发一种无金属合成策略.
- 精确调整光带间隙和CMP的表面积.
- 建立一种可控的CMP制造方法,使用酸催化.
主要方法:
- 在CMP的现场循环反应.
- 没有金属的合成方法.
- 使用不同酸强度的酸催化剂 (pKa) 控制反应条件.
主要成果:
- 在2.07和3.35 eV之间实现CMP光波段间隙的精确调整.
- 证明了CMP光带间隙与酸催化剂的pKa之间的线性关系.
- 合成的CMP具有优良的纹理特性,包括微孔性和高的特定表面积.
- 成功避免使用贵金属催化剂.
结论:
- 开发的无金属现场循环化为合成CMP提供了强大而可控的方法.
- 这种策略可以在可见太阳光谱范围内精确调整光带间隙.
- 由于其可调节的电子和纹理特性,合成的CMP具有各种应用的理想特性.
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