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相关概念视频

Metallic Solids02:37

Metallic Solids

20.8K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.8K
Bonding in Metals02:32

Bonding in Metals

52.5K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
52.5K
Alkali Metals03:06

Alkali Metals

24.8K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
24.8K
Dietary Connections01:23

Dietary Connections

62.1K
In biological systems, most metabolic pathways are interconnected. The cellular respiration processes that convert glucose to ATP—such as glycolysis, pyruvate oxidation, and the citric acid cycle—tie into those that break down other organic compounds. As a result, various foods—from apples to cheese to guacamole—end up as ATP. In addition to carbohydrates, food also contains proteins and lipids—such as cholesterol and fats. All of these organic compounds are used...
62.1K
Metal-Ligand Bonds02:51

Metal-Ligand Bonds

24.4K
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
24.4K
Properties of Transition Metals02:58

Properties of Transition Metals

29.9K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
29.9K

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相关实验视频

Updated: Feb 6, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
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具有4个连接的Zr6节点的灵活金属有机框架

Yuanyuan Zhang1,2, Xuan Zhang2, Jiafei Lyu2

  • 1Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry and Chemical Engineering , Beijing Institute of Technology , Beijing 100081 , People's Republic of China.

Journal of the American Chemical Society
|August 17, 2018
PubMed
概括

我们开发了NU-1400,一种基于的柔性金属有机框架 (Zr-MOF). 这种材料表现出严重的依赖客体的结构变化,影响其对化学应用的反应性.

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科学领域:

  • 材料科学
  • 化学学
  • 纳米技术

背景情况:

  • 基于的金属有机框架 (Zr-MOF) 以其强大的稳定性而闻名.
  • 由于Zr6节点的高连接性,Zr-MOF难以实现灵活性.

研究的目的:

  • 设计和合成具有可调节结构性质的柔性Zr-MOF.
  • 研究依赖客体的结构灵活性及其对化学反应性的影响.

主要方法:

  • 一种新的柔性Zr-MOF,NU-1400的合成,使用4连接的Zr6节点和四层连接器.
  • 单晶X射线衍射分析结构变化.
  • 对神经毒剂模拟剂的反应性评估.

主要成果:

  • NU-1400具有显著的依赖客体的结构灵活性,单位细胞体积收缩高达48%.
  • 扩展和收缩的NU-1400表现出不同的反应性.
  • 不同形状的尺寸选择性影响反应剂的可访问性和反应速度.

结论:

  • 开发NU-1400证明了在Zr-MOF中引入灵活性的成功策略.
  • 观察到的结构灵活性和尺寸选择性为催化和传感中量身定制的应用提供了潜力.
  • 这项工作为设计响应和适应性的金属有机框架材料开辟了新的途径.