一种半导体结合基聚物:双极氧化活性和法拉第效应
Pan Wang1,2, Sibo Lin1, Zhou Lin1
1Department of Chemistry , Massachusetts Institute of Technology , Cambridge , Massachusetts 02139 , United States.
Journal of the American Chemical Society
|August 22, 2018
概括
基于1,3- bisdiphenylene-2-phenylallyl (BDPA) 的结合基聚合物表现出两极性氧化还原活性和导电性. 这些新材料显示出磁光 (MO) 材料的潜力,与无机对应物竞争.
科学领域:
- 材料科学
- 有机电子
- 磁力学
背景情况:
- 对光子和磁器件进行探索,提供可调节的磁性.
- 将基质物种整合到导电聚合物骨干中仍然是一个早期的研究领域.
- 之前的研究集中在具有绝缘骨架的激进聚合物上.
研究的目的:
- 合成和表征基于1,3-双二烯 (BDPA) 的结合基聚合物.
- 研究它们的氧化还原活性,导电性和磁光学 (MO) 特性.
- 评估它们作为先进的MO材料的潜力.
主要方法:
- 合成基于BDPA的结合基聚合物.
- 电化学分析用于减氧活性和导电性测量.
- 磁光效应的表征,包括法拉第旋转和维德特常数.
主要成果:
- 合成的结合基聚合物表现出两极性氧化还原活性和电导性.
- 这些聚合物表现出显著的法拉第旋转,其标志因基质特征而调节.
- 在532nm达到2.80±0.84×10^4°T^-1m^-1的绝对Verdet常数,与商业无机MO材料相比.
结论:
- 多功能结合基聚合物作为响应性磁光材料具有前景.
- 激进物种融入导电聚合物骨干为材料设计开辟了新的途径.
- 基于BDPA的聚合物为无机磁光材料提供了可行的有机替代品.
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