来自Achiral生物金属有机框架的手术活动
Li-Li Xu1,2, Hai-Feng Zhang1, Mian Li1
1Department of Chemistry , Shantou University , Guangdong 515063 , P. R. China.
Journal of the American Chemical Society
|August 25, 2018
概括
由于其晶体对称性,Achiral金属有机框架 (MOF) 可以表现出手术活动. 这项研究报告了第一个Achiral MOF,ZnFDCA,证明了这种罕见的现象.
科学领域:
- 材料科学
- 晶体学
- 光学学
背景情况:
- 石眼活动通常与性分子相关.
- 具有光学活性的Achiral晶体在理论上是可能的,但很少被观察到.
- 金属有机框架 (MOF) 提供可调节的结构来探索材料特性.
研究的目的:
- 调查金属有机框架 (MOF) 中的手术活动.
- 展示一个光学活跃的Achiral MOF的第一个例子.
- 探索MOF中的晶体对称性和手术性质之间的关系.
主要方法:
- 合成含有腺因的MOF (ZnFDCA和ZnFDCA-NH2).
- 晶体结构和对称性的描述.
- 测量循环二光学 (CD) 信号以评估手术活动.
主要成果:
- 基MOFZnFDCA表现出明显的手术活动,由强烈的对立CD信号证明.
- 这种活性归因于ZnFDCA的内在4̅2m晶体对称性.
- 修改MOF (ZnFDCA-NH2) 导致中心对称的晶体结构,消除了手术和非线性光学活动.
结论:
- 状MOF可以显示手术活动,挑战传统的理解.
- 晶体对称性是无晶体材料中光学特性的一个关键决定因素.
- ZnFDCA 是一种新型材料,在光学技术中具有潜在的应用.
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