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具有效率超过15的太阳能电池的二维Ruddlesden-Popper矿
Hongtao Lai1, Bin Kan1, Tingting Liu1
1The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, Institute of Polymer Chemistry, College of Chemistry , Nankai University , Tianjin 300071 , People's Republic of China.
Journal of the American Chemical Society
|August 31, 2018
概括
研究人员开发了一种新的2D矿太阳能电池,使用2-thiophenemethylammonium (ThMA) 作为间隔离子. 这项创新显著提高了光伏的性能和稳定性,使二维矿太阳能电池的效率超过15%.
科学领域:
- 材料科学
- 可再生能源
- 固态物理
背景情况:
- 两个维的Ruddlesden-Popper矿为太阳能电池提供了环境稳定性.
- 然而,二维矿通常具有有限的光伏性能.
研究的目的:
- 为提高太阳能电池性能和稳定性开发一种新的二维矿材料.
- 研究膜形成机制及其对光伏性能的影响.
主要方法:
- 合成了一种新的2D矿,使用2-thiophenemethylammonium (ThMA+) 作为间隔离子.
- 使用甲基化物 (MACl) 辅助薄膜成形技术在N,N-二甲基形式胺中沉积高度定向的薄膜.
- 描述了膜的形态,结晶性和结晶的方向.
主要成果:
- 在二维矿太阳能电池中实现了超过15%的功率转换效率 (n=3),这是n<6个设备的记录.
- 与3D矿相比,其稳定性得到了提高.
- 观察到密集的,类似纳米片的薄膜,具有近乎单晶的质量和优选的晶体方向.
结论:
- 使用MACl处理的基于ThMA+的二维矿显著提高了光伏性能和稳定性.
- 这种效率的提高归因于高度定向的晶体薄膜,
- 这项研究为制造具有可控晶度和方向的高性能二维矿太阳能电池提供了洞察力.
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