基于三烯的共价有机框架:在离子热条件下的构造和结构转换
Hongtao Wei1, Jing Ning1, Xingdi Cao1
1College of Chemistry and Pharmaceutical Sciences , Qingdao Agricultural University , No.700 Changcheng Road , Qingdao 266109 , China.
Journal of the American Chemical Society
|September 5, 2018
概括
研究人员合成了一种新型的C3对称三甲 (BTT),以创建共价有机框架 (COF). 这些基于BTT的COF具有可控制的结构和高导电性,可用于超级电容.
科学领域:
- 材料科学
- 电化学
- 有机化学
背景情况:
- 共价有机框架 (COF) 是具有可调节性质的多孔晶体材料.
- 三烯 (BTT) 衍生物具有独特的电子和结构特性.
- 开发功能性COF的高效合成方法对于高级应用至关重要.
研究的目的:
- 合成一种新型的C3对称三甲 (BTT) 构建块.
- 构建不同孔径的基于BTT的COF并研究它们的结构转换.
- 探索COF结构和超级电容器性能之间的关系.
主要方法:
- 容易合成C3对称的BTT三碳甲.
- 构建不同孔径的基于BTT的COF.
- 高温离子热处理以进行受控的结构改造.
- 超级电容器性能评估的电化学特征.
主要成果:
- 成功合成BTT三碳化合物及其在COF建筑中的使用.
- 在离子热条件下对COF结构演变的系统研究.
- 结构可控制的高导电性COF的演示.
- 特定的COF结构与增强的超级电容器性能之间的相关性.
结论:
- 一种简单的合成BTT三碳化合物的方法可以产生多种COF.
- 离子热处理是定制COF结构和特性的一个有效策略.
- 基于BTT的COF是高性能电化学储能材料,特别是超级电容器.
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