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Updated: Feb 5, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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解开N-异环碳化合物和循环 (基) ((氨基) 碳化合物稳定低主群物种之间的显著电结构差异

Eileen Welz1, Julian Böhnke2,3, Rian D Dewhurst2,3

  • 1Institute for Physical and Theoretical Chemistry , Julius-Maximilians-Universität Würzburg , Am Hubland , 97074 Würzburg , Germany.

Journal of the American Chemical Society
|September 6, 2018
PubMed
概括

循环 (基) 氨基) 碳化合物 (CAAC) 和N-异环碳化合物 (NHC) 在稳定性方面因单环三环间隙而不同,而不仅仅是硬质或电子效应. 分子轨道的考量揭示了这些差距是理解它们独特行为的关键.

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