聚合物Pd/Au稀释合金纳米晶体的合成及其选择性催化氧化潜力
Cody J Wrasman1, Alexey Boubnov2, Andrew R Riscoe1
1Department of Chemical Engineering and SUNCAT Center for Interface Science and Catalysis , Stanford University , Stanford , California 94305 , United States.
Journal of the American Chemical Society
|September 18, 2018
概括
稀释的金纳米晶体提供优越的选择性氧化2-propanol的乙. 在黄金表面上分离的原子产生协同效应,增强催化性能和高效的贵金属利用.
科学领域:
- 催化剂
- 材料科学
- 纳米技术
背景情况:
- 选择性氧化对于化学合成至关重要,但与传统氧化剂和单位催化剂面临挑战.
- 双金属合金提供可调节的选择性,但合成控制仍然是精确表面化学修改的障碍.
研究的目的:
- 合成稀释金 (Pd/Au) 合金的状纳米晶体.
- 研究Pd/Au表面成分对2-propanol选择性氧化的协同作用.
- 了解孤立活性位点在增强催化性能中的作用.
主要方法:
- 合金Pd/Au纳米晶体的合成.
- 在 (TiO2) 上使用纳米晶体支.
- 纳米晶体结构和表面组成的特征.
- 测试2-醇氧化的催化活性和选择性.
主要成果:
- 调整Pd/Au表面比率显著增强了2-醇对的选择性氧化.
- 与纯Pd或Au催化剂相比,某些Pd/Au组合显示出更高的性能.
- 结构分析显示孤立的Pd原子是最有效的催化剂中的关键活性位点.
结论:
- 隔离的Pd原子和Au之间的协同作用可以通过氧化物中间体进行选择性氧化,抑制完全的燃烧.
- 这种方法可以有效地利用贵金属,并为选择性氧化催化提供新的途径.
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