金属化物集群的蓝色发射单晶组件
Chenkun Zhou1, Haoran Lin1, Michael Worku2
1Department of Chemical and Biomedical Engineering , FAMU-FSU College of Engineering , Tallahassee , Florida 32310 , United States.
Journal of the American Chemical Society
|September 20, 2018
概括
研究人员使用化集群开发了一种新的零维 (0D) 有机-无机混合材料. 这种晶体组合具有高效的蓝光发射,为可调节的功能材料开辟了新的途径.
科学领域:
- 材料科学
- 无机化学
- 晶体学
背景情况:
- 有机-无机金属化物混合物提供多样化的晶体结构.
- 控制形态和分子维度是关键的研究领域.
研究的目的:
- 报告第一个单晶金属化物集群.
- 描述它的结构和光发光特性.
主要方法:
- 有机-无机混合材料的合成.
- 用X射线衍射进行结构分析.
- 用于光学性能评估的光发光谱学.
主要成果:
- 由同结晶的四面体 (PbCl4^2-) 和有机离子 (C9NH20^+) 的三元集群 (Pb3Cl11^5-) 形成的独特的零维 (0D) 结构.
- 实现高光发光量子效率 (PLQE) ~83%的蓝光发射 (峰值在470nm).
- 对单个化集群的发光归因.
结论:
- 发现了一种新的单晶金属化物集群.
- 在功能集群中展示高度可调的结构和显著的特性.
- 开辟了先进发光材料的新途径.
相关概念视频
Bonding in Metals
52.5K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”.
52.5K
Alkali Metals
24.8K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
24.8K
Polymer Classification: Crystallinity
4.0K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
4.0K
Metallic Solids
20.7K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.7K
Alkyl Halides
20.0K
Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
20.0K
Acid Halides to Esters: Alcoholysis
4.0K
Alcoholysis is a nucleophilic acyl substitution reaction in which an alcohol functions as a nucleophile. Acid halides react with alcohol to produce esters. The mechanism proceeds in three steps:
4.0K


