作为灵活的白光发射器的合性有机框架
Sattwick Haldar, Debanjan Chakraborty, Bibhisan Roy
1Department of Physics , Indian Institute of Technology , Mumbai , 400076 India.
Journal of the American Chemical Society
|September 27, 2018
概括
研究人员开发了一种新的共价有机框架 (COF) 用于白光发射. 这种材料被纳入聚合物中,可以为先进的固态照明应用提供无溶剂的单源白光发射器.
科学领域:
- 材料科学
- 有机化学
- 固态照明
背景情况:
- 共价有机框架 (COF) 为高级应用提供可调节的电子特性.
- 开发高效的单源白光发射器对于下一代固态照明至关重要.
- 将功能部分纳入COF可以实现协作式电子行为.
研究的目的:
- 设计和合成一种基于COF的新材料,用于发射白光.
- 研究固态照明的COF的机制和可处理性.
- 展示COF作为单源白光发射器的潜力.
主要方法:
- 合成一种以素为基础的COF.
- 光学属性的表征,包括稳定状态和时间分辨率光谱.
- 将COF纳入一个聚甲酸 (PMMA) 聚合物基质.
主要成果:
- 合成的COF表现出由于醇分离体的双发射,使白光发射成为可能.
- 在PMMA中COF的低负荷 (0.32%) 产生强烈白光的无溶剂薄膜 (CIE坐标为 (0.35,0.36).
- 白色光的发射机制被确定为光,由素和素单元的独特贡献.
结论:
- 这项研究引入了基于COF的新一类易于处理的单源白光发射器.
- 设计的COF显示可调节的双排放,适用于固态照明应用.
- 在COF结构中的合作电子功能是其白光发射特性的关键.
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