通过氨基功能化共价有机框架从水中去除GenX和化基物质
Woojung Ji1, Leilei Xiao1,2, Yuhan Ling3
1Department of Chemistry , Northwestern University , Evanston , Illinois 60208 , United States.
Journal of the American Chemical Society
|September 27, 2018
概括
使用初级氨基的新型共价有机框架 (COF) 能够有效地从水中去除有害的多化基物质 (PFAS). 这些有前途的吸附剂为广泛的PFAS污染提供了潜在的解决方案.
科学领域:
- 环境化学
- 材料科学
- 纳米技术
背景情况:
- 和多基物质 (PFAS) 是水源中持续存在的全球污染物.
- 目前的PFAS清除技术面临成本和性能限制.
- 协价有机框架 (COF) 具有较大的表面积和可调节的吸附性能.
研究的目的:
- 调查与原始胺结合的二维COFs对于PFAS去除的潜力.
- 了解COF结构与GenX吸附效率之间的关系.
- 确定优化COF吸附剂的设计标准,以对PFAS进行整治.
主要方法:
- 合成具有不同初级氨基的二维COF.
- 在环境相关度下使用GenX和13个PFAS的吸附实验.
- 对COF特性和吸附动力学和容量的分析.
主要成果:
- 部分含有氨基的COF显示出GenX的快速吸附.
- 在COF中最佳的氨基负荷 (28%) 导致GenX的高容量和快速去除.
- 在13个测试的PFAS中,该研究的COF清除了90%以上.
- 极性氨基群和疏水性COF表面之间的协同作用增强了PFAS的结合.
结论:
- 含有初级氨基的二维COF是GenX和其他PFAS的高效吸附剂.
- 部分氨基合并和特定的表面化学是最大化吸附性能的关键.
- 碳酸是开发先进 PFAS 水处理技术的一类有前途的材料.
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