在一个看似难以穿透的结框架中,通过便利运输来交流客人
Yuantao Li1, Marcel Handke1, Yu-Sheng Chen2
1Department of Chemistry and Molecular Design Institute , New York University , 100 Washington Square East, Room 1001 , New York , New York 10003 , United States.
Journal of the American Chemical Society
|September 29, 2018
概括
通过单晶到单晶的转换实现了关尼主机框架中的客户交换. 这种工艺使得黄可以融入以前无法进入的口袋,从而显示出快速的客人交换.
科学领域:
- 超分子化学
- 材料科学
- 晶体学
背景情况:
- 关尼1,3,5-三4-硫 (G3TSPHB) 与客分子形成了包括化合物.
- 主机框架包含孤立的口袋, 给客人交流带来挑战.
研究的目的:
- 在G3TSPHB中使用单晶到单晶转换 (SCSCT) 调查客户交换.
- 阐明将六二 (HFB) 纳入宿主框架的机制.
主要方法:
- 单晶X射线衍射用于监测SCSCT期间的结构变化.
- 光学和拉曼显微镜观察中间阶段和客体动态.
- 客人交换过程的现场分析.
主要成果:
- 在G3TSPHB框架下,SCSCT使客人能够与HFB交换异.
- 在转化过程中,晶体对称性从单晶变为六角形.
- 形成并凝聚在一起, 便于快速的客人运输.
结论:
- 在多孔晶体材料中提供有效的客户交换途径.
- 沿着叶片接口的便利运输加速了客体的扩散.
- 这项研究展示了一种修改以前无法访问的客体的纳入化合物的方法.
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