化纳米晶体的压力诱导大排放增强
Guanjun Xiao1, Yingnan Wang2, Dong Han3
1State Key Laboratory of Superhard Materials, College of Physics , Jilin University , Changchun 130012 , China.
Journal of the American Chemical Society
|September 29, 2018
概括
我们发现压缩化纳米晶体 (CdSe NCs) 显著增加它们的光辐射,克服了光学压力传感器的关键限制. 这种增强为压力传感和光成像应用开辟了新的途径.
科学领域:
- 材料科学
- 纳米技术
- 光学学
背景情况:
- 在压力传感器中的光学排放极限应用的压力诱导灭.
- 在高压下增强可见光的发射对于设备的性能至关重要.
研究的目的:
- 证明和研究化纳米晶体 (CdSeNCs) 中压力诱导的光学辐射增强.
- 探索导致排放增加的潜在机制.
- 在光学压力传感和光成像中确定CdSeNC的潜力.
主要方法:
- 将CdSe纳米晶体 (NC) 压缩到高压的实验.
- 光学发射光谱测量发光强度.
- 研究电子结构和表面相互作用的第一原则计算.
主要成果:
- 在压缩时,CdSe NC显示了光学辐射的数量级增强.
- 在压力与CdSeNC相位过渡相吻合时观察到最明亮的辐射.
- 增加带间隙与压力导致非常明亮的蓝色辐射.
- 第一个原理的计算显示了增强的油酸 (OA) 层相互作用和在高压下增加的希尔什菲尔德电荷.
- 表面重建和消除陷状态被确定为增强排放的关键因素.
结论:
- 压缩有效地增强了CdSeNC的光学发射,克服了压力灭的限制.
- 观察到的增强归因于压力诱导的表面重建和改变的表面核心相互作用.
- 这些发现使得新型光学压力传感器 (压力纳米仪) 和可调的光成像系统的开发成为可能.
相关概念视频
Emission Spectra
76.4K
When solids, liquids, or condensed gases are heated sufficiently, they radiate some of the excess energy as light. Photons produced in this manner have a range of energies, and thereby produce a continuous spectrum in which an unbroken series of wavelengths is present.
76.4K
Vapor Pressure
40.8K
When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules move randomly about, they will occasionally collide with the surface of the condensed phase, and in some cases, these collisions will result in the molecules re-entering the condensed phase. The change from the gas phase to the liquid is called condensation. When the rate of condensation becomes equal to the rate of vaporization, neither the amount of the liquid nor the amount of the vapor...
40.8K
Positron Emission Tomography
7.4K
Positron emission tomography (PET) is a medical imaging technique involving radiopharmaceuticals — substances that emit short-lived radiation. Although the first PET scanner was introduced in 1961, it took 15 more years before radiopharmaceuticals were combined with the technique and revolutionized its potential.
One of the main requirements of a PET scan is a positron-emitting radioisotope, which is produced in a cyclotron and then attached to a substance used by the part of the body...
One of the main requirements of a PET scan is a positron-emitting radioisotope, which is produced in a cyclotron and then attached to a substance used by the part of the body...
7.4K
Definition and Measurement of Pressure: Atmospheric Pressure, Barometer, and Manometer
43.4K
Gas pressure is caused by force exerted by gas molecules colliding with the surfaces of objects. Although the force of each collision is very small, any surface of an appreciable area experiences a large number of collisions in a short time, which can result in high pressure.
43.4K
Self-Evaluation: Self-Enhancement and Self-Verification
5.8K
Social psychologists have documented that feeling good about ourselves and maintaining positive self-esteem is a powerful motivator of human behavior (Tavris & Aronson, 2008). In the United States, members of the predominant culture typically think very highly of themselves and view themselves as good people who are above average on many desirable traits (Ehrlinger, Gilovich, & Ross, 2005). Often, our behavior, attitudes, and beliefs are affected when we experience a threat to our...
5.8K
Bioavailability Enhancement: Drug Solubility Enhancement
261
Body:Bioavailability is a critical factor in determining a drug's effectiveness. It refers to the proportion of a drug that enters the circulation when introduced into the body and is, as a result, able to have an active effect. Enhancing bioavailability is essential for drugs with poor solubility, as it can significantly impact their therapeutic efficacy. Various methods are employed to increase the solubility of drugs, thereby enhancing their bioavailability.Micronization and nanonization are...
261


