用于适应性客体包容的共价有机框架的分子编织
Yuzhong Liu1, Yanhang Ma2, Jingjing Yang1
1Department of Chemistry, University of California-Berkeley, and Materials Sciences Division , Lawrence Berkeley National Laboratory, Kavli Energy NanoSciences Institute , Berkeley , California 94720 , United States.
Journal of the American Chemical Society
|October 2, 2018
概括
合成了新的编织共价有机框架 (COF),并表现出独特的孔隙动力学. COF-506 证明了
科学领域:
- 材料科学
- 化学学
- 纳米技术
背景情况:
- 共价有机框架 (COF) 是晶体多孔聚合物.
- 设计具有受控毛孔大小的非透性COF具有挑战性.
- 合金COF具有可调节的特性,并有可能实现新的功能.
研究的目的:
- 合成新的异构质非穿透性COF.
- 研究合成的COF的客户可访问性和孔状动态.
- 将新COF的特性与现有的相互透的框架进行比较.
主要方法:
- 化COF-506-Cu的合成使用化功能化铜 (I) 复合物和司丁连接剂.
- 通过COF-506-Cu的脱,获得COF-506.
- 通过粉末X射线衍射和电子显微镜来确定结构.
- 使用蒸汽和染料入实验的客人可访问性研究.
主要成果:
- 已成功合成异构型非透性织物COF (COF-506-Cu和COF-506).
- COF-506表现出比其毛孔大小更大的客分子的显著吸收.
- 这种现象表明固体中存在一种新的"适应性包容"机制.
结论:
- 合成的COF具有独特的结构和动态特性.
- COF-506的"适应性包含"行为为客户封装开辟了新的途径.
- 这项研究有助于我们更好地了解多孔材料中的动态过程.
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