测量热塑性纳米结构的表面温度
Shu Hu1, Bi-Ju Liu1, Jia-Min Feng1
1State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), The MOE Key Laboratory of Spectrochemical Analysis & Instrumentation, Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen University , Xiamen 361005 , China.
Journal of the American Chemical Society
|October 4, 2018
概括
这项研究引入了一种新的表面增强拉曼光谱法,用于精确测量热质纳米结构的温度. 这种技术可用于光热疗法和细胞温度计的表面温度监测.
科学领域:
- 纳米技术
- 光谱学
- 生物物理
背景情况:
- 对热质纳米结构的精确表面温度测量对于光热疗法等应用至关重要.
- 现有的方法缺乏直接测量这些纳米结构的表面温度的能力.
研究的目的:
- 开发一种使用表面增强拉曼光谱测量等离子体纳米结构表面温度的新方法.
- 验证该方法的准确性,并将其应用于单活细胞温度计.
主要方法:
- 在纳米结构上吸附的异化物分子的拉伸振动中利用温度依赖的变化.
- 使用表面增强的拉曼光谱 (SERS) 进行敏感的温度检测.
- 通过监测来自金纳米粒子表面的激光诱导的二氧化碳脱落来验证该方法.
主要成果:
- 观察到与分子定向变化相关的异拉伸振动的敏感温度变化 (0. 232 cm-1 / °C).
- 基于SERS的方法在等离子激发过程中准确地测量了金纳米粒子表面温度.
- 该技术成功地用于监测单个活细胞中的细胞外温度分布和细胞内温度变化.
结论:
- 表面增强的拉曼光谱为精确的热质纳米结构表面温度测量提供了强大而新的方法.
- 这种方法提供了高空间分辨率,使细胞温度计的先进应用和理解生物系统中的热效应成为可能.
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