在单个Diketopyrrolopyrrole连接处的共振传输
Yaping Zang1, Suman Ray2, E-Dean Fung1
1Department of Applied Physics and Applied Mathematics , Columbia University , New York , New York 10027 , United States.
Journal of the American Chemical Society
|October 4, 2018
概括
狄克托皮洛皮洛寡合物表现出高效的单分子电荷传输. 在高偏差下,可以观察到共振传输,证明它们对分子电子学的潜力.
科学领域:
- 材料科学
- 分子电子
- 有机半导体
背景情况:
- 基基 (DPP) 寡合体是有前途的有机半导体.
- 了解单分子设备中的电荷传输对于分子电子学至关重要.
- 之前的研究已经探讨了DPP的特性,但远程运输机制需要进一步研究.
研究的目的:
- 研究不同长度的单分子二甲基烯酸寡合体 (DPP n,n = 1-4) 的运输特性.
- 阐明不同偏差电压的传输机制.
- 评估DPP衍生品在高效远程电荷传输方面的潜力.
主要方法:
- 对DPP寡合体 (1-5 nm长度) 的单分子导电性的实验测量.
- 适用于探测器传输模式的可变偏差电压.
- 基于密度函数理论 (DFT) 的计算以建模运输特性.
主要成果:
- 在低偏差下,电导率会随长度呈指数衰减,这是非共振传输的典型特征.
- 在高偏差下,极高的导电率 (约. 在所有DPP寡合体中观察到10^-2G0) 和电流 (> 0. 1μA).
- DFT计算支持由于DPP背骨脱位而导致的高偏差的共振传输机制.
结论:
- DPP寡合物具有高效的远程电荷传输能力.
- 一个高偏差的共振传输的过渡是高导电的原因.
- 对于单分子电子设备的应用,DPP衍生物具有显著的前景.
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