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用三甲基衍生物探测保利排斥和伦敦分散之间的微妙平衡

Sören Rösel1, Jonathan Becker2, Wesley D Allen

  • 1Institute of Organic Chemistry , Justus Liebig University , Heinrich-Buff-Ring 17 , 35392 Giessen , Germany.

Journal of the American Chemical Society
|October 6, 2018
PubMed
概括

伦敦分散相互作用显著稳定了六乙烯 (HPE) 衍生物. 像阿达曼提尔这样的大型,刚性碳化合物组通过有利的几何适配和强大的分子内分散力来增强HPE的稳定性,即使在溶液中.

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