在半导体单壁碳纳米管中产生光学自由载体的定量评估
Yusong Bai1, George Bullard1, Jean-Hubert Olivier1
1Department of Chemistry, French Family Science Center , Duke University , Durham , North Carolina 27708-0346 , United States.
Journal of the American Chemical Society
|October 6, 2018
概括
在单壁碳纳米管 (SWNT) 中量化自由载体生成对光电子非常重要. 这项研究开发了一种光谱方法来测量SWNT中的光学FCG产量,揭示介质和激发影响.
科学领域:
- 材料科学
- 光电子产品
- 光谱学
背景情况:
- 单壁碳纳米管 (SWNT) 中的自由载体生成 (FCG) 对光电子非常重要.
- 之前的研究由于SWNT样本异质性和模两可的签名而缺乏定量方法.
- 了解FCG是SWNT设备中高效的光子到电流转换的关键.
研究的目的:
- 开发一种简单的定量方法来评估SWNT中的光驱FCG.
- 使用超快光谱学将FCG与三离子形成动态相关联.
- 研究激发能和中介介电介强度对FCG量子产量的影响.
主要方法:
- 使用超快的探测谱在度丰富,长度排序的SWNT.
- 用于FCG定量化的三离子暂时吸收特征.
- 确定三离子吸收横截面来计算FCG量子产量.
主要成果:
- 确立了FCG和快速三离子形成动态 (<1 ps) 之间的直接相关性.
- 与E22和E11相比,E33激子显著提高了FCG的量子产量.
- 通过增加溶剂介电常数 (从5%到18%) 证明了FCG量子产量的单调增加.
结论:
- 这项研究提供了一种可靠的方法来定量评估SWNT中的FCG.
- 激发条件和介质特性对FCG的量子产量有着重要的控制作用.
- 这些发现为优化基于SWNT的光探测器和光伏提供了设计见解.
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