用于高流量有机溶剂纳米过的晶体二维共价有机框架膜
Digambar B Shinde1, Guan Sheng1, Xiang Li1
1Advanced Membranes and Porous Materials Center, Division of Physical Science and Engineering , King Abdullah University of Science and Technology (KAUST) , Thuwal , Saudi Arabia.
Journal of the American Chemical Society
|October 6, 2018
概括
我们开发了一个新的二维共价有机框架 (COF) 膜,用于高性能分离. 这种晶体COF膜在有机溶剂过中实现了高流量和选择性.
科学领域:
- 材料科学
- 化学工程
- 纳米技术
背景情况:
- 二维 (2D) 共价有机框架 (COF) 材料为先进的膜应用提供了有前途的微结构.
- 实现高流量和高选择性仍然是膜科学中的一个关键挑战.
研究的目的:
- 合成和描述一个晶体TFP-DHF2DCOF膜,以高效地分离有机溶剂.
- 研究新型二维COF膜的传输机制和性能.
主要方法:
- 使用1,3,5-三黄 (TFP) 和9,9-二二胺 (DHF) 前体合成晶体TFP-DHF二维COF膜.
- 通过Langmuir-Blodgett (LB) 方法制造,使其能够逐层转移到氧化物 (AAO) 等多孔支物上.
主要成果:
- TFP-DHF 2D COF 膜具有显著更高的透性 (大约为 与无形膜相比,对于有机溶剂来说是100倍.
- 具有显著的分子选能力,分子重量保留开始 (MWRO) 约为600Da,分子重量切断 (MWCO) 约为900Da.
- 运输机制被确定为具有强烈滑动边界增强的粘性流,与无形聚合物膜不同.
结论:
- 两维COF膜的有序多孔结构对于其增强的分离性能至关重要.
- 作为下一代高性能膜应用材料,二维COF具有巨大的潜力.
- 开发的膜为极性和非极性有机溶剂的有效分离提供了一个有前途的平台.
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