金纳米结构的压力诱导阶段工程
Qian Li1, Wenxin Niu2, Xingchen Liu3,4
1Department of Chemistry , Southern University of Science and Technology (SUSTech) , Shenzhen , Guangdong 518055 , P. R. China.
Journal of the American Chemical Society
|October 23, 2018
概括
研究人员使用高压实现了金纳米丝带从六边形4H到面中心立方体 (fcc) 的不可逆转相变. 这种压力诱导的相位工程可以控制黄金纳米结构的特性.
科学领域:
- 材料科学
- 纳米技术
- 物理化学
背景情况:
- 黄金 (Au) 等贵金属的相工程对于基础研究和应用至关重要.
- 控制黄金纳米结构的晶体阶段仍然是湿化学合成的一个重大挑战.
研究的目的:
- 研究金纳米带 (NRB) 的压力诱导相变.
- 展示金纳米结构的相位工程方法.
- 在4H到fcc相位过渡过程中阐明基于原子的转换路径.
主要方法:
- 六角4H金纳米带的高压处理.
- 阶段转换的实验性表征.
- 支持转换机制的第一原则计算.
主要成果:
- 在Au NRB中通过高压实现了从六边形4H到面中心立方 (fcc) 阶段的不可逆转转变.
- 在回收的AuNRB中,4H和fcc相的比例可以通过峰值压力控制.
- 与纯4H AuNRB相比,晶相异构的4H/fcc纳米棒具有较低的过渡压力和更窄的范围.
- 基于原子的转换途径被实验揭示并得到计算支持.
结论:
- 证明了4H金纳米结构的稳定性.
- 揭示了金纳米结构中压力诱导的4H到fcc相变的机制.
- 提供了高贵金属纳米结构相位工程的新策略.
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