从稀土元素中选择性提取
Zijie Wang1, Alexander T Brown1, Kui Tan2
1Department of Chemistry and Biochemistry , 800 West Campbell Road , University of Texas at Dallas , Richardson , Texas 75080 , United States.
Journal of the American Chemical Society
|October 24, 2018
概括
一种新的多孔碳材料,WMC-O,从稀土元素中选择性地提取. 这种可重复使用的固态吸收剂比传统的液体-液体提取为生产提供了显著的优势.
科学领域:
- 核工程
- 材料科学
- 分析化学
背景情况:
- 液体化反应堆比反应堆提供经济和环境优势.
- 的生产需要将其从矿物中发现的稀土元素中分离出来.
- 传统的分离方法使用液体-液体提取,需要开发可重复使用的固态替代品.
研究的目的:
- 开发一种用于选择性离子提取的新型固态吸收剂.
- 评估表面氧化纹介质碳 (WMC-O) 在分离稀土离子中的性能.
- 评估WMC-O的可重复使用性和吸附能力.
主要方法:
- 表面氧化纹半孔碳 (WMC-O) 的合成.
- 吸附实验以确定和稀土离子的分布系数 (Kd).
- 用表面氧化活性炭对WMC-O进行比较分析.
主要成果:
- WMC-O对离子 (Th4+) 和稀土离子具有很高的选择性.
- 使用WMC-O的的分布系数与pH2.15的活性炭 (Kd = 35 × 10^2) 相比显著更高 (Kd = 13 × 10^4).
- 对于纯稀土离子,WMC-O具有很高的吸附能力 (Kd > 3 × 10^5).
结论:
- 表面氧化纹介质碳 (WMC-O) 是一种高度选择性和有前途的取吸收剂.
- WMC-O提供了有效的稀土离子回收的潜力.
- 该材料的特性支持其在先进的核燃料循环应用中使用.
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